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pro vyhledávání: '"Jae Youp Cheong"'
Autor:
Jae Youp Cheong, Young Ho Rhee
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 7, Iss 1, Pp 740-743 (2011)
An efficient formal total synthesis of (±)-clavukerin A was accomplished via a gold-catalyzed cycloisomerization of a 3-methoxy-1,6-enyne 5 as the key strategy followed by Rh-catalyzed stereoselective hydrogenation of the cycloheptenone 4.
Externí odkaz:
https://doaj.org/article/b7d070597b6d46699e31292d9ce8587d
Publikováno v:
The Journal of Organic Chemistry. 76:324-327
The Au(I)-catalyzed reactions of 5-allyloxy-1-ynes gave various γ-hydroxyketones, via a hydration-terminated domino sequence involving sigmatropic allyl migration as the key event. Moreover, the scope of the sigmatropic allyl transfer was systematic
Publikováno v:
Journal of Organic Chemistry; 1/7/2011, Vol. 76 Issue 1, p324-327, 4p