Zobrazeno 1 - 10
of 64
pro vyhledávání: '"Jacques E. Collin"'
Autor:
Iv. L'Acétone, Jacques E. Collin
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 76:273-289
A mass spectrometric investigation of the thermal decomposition of acetone in a quartz reactor has been undertaken, in the 40–200 microns pressure range, in the absence of a carrier gas. The analysis of the results shows that below 400°C acetone u
Autor:
Jacques E. Collin
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 72:38-49
Dans le but de comparer la resistance des molecules a l'impact electronique et aux radiations, on evalue sur la base de leur spectre de masse, la stabilite relative d'une serie de molecules a caractere aromatique, soumises au bombardement electroniqu
Autor:
Jacques E. Collin
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 73:414-427
A short survey of some of the most interesting and recent developments in ionization studies is made. Attention is particularly called upon such problems as vibrational structure of ionization curves, autoionization phenomena, anomalies in critical v
Autor:
Jacques E. Collin, A. Delplace
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 75:304-320
The thermal behavior of acetaldehyde, at pressures of the order of 100 microns, has been investigated, up to 750°C, in a quartz reactor connected to a TOF Bendix mass spectrometer. In those conditions, no methane formation has been observed. Two imp
Autor:
Jacques E. Collin
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 69:585-592
A study of the mass spectra of dioxygenated heterocyclic compounds is made and an interpretation of the cracking patterns proposed. A comparison with furanic derivatives has been established and discussed.
Autor:
Jacques E. Collin, E. De Pauw
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 93:355-368
Electron spin resonance has been chosen to monitor the radical species occuring during photoexcitation of selected aromatic-cetone charge transfer complexes. The identification of trapped intermediate radicals is presented and the relation between re
Autor:
Jacques E. Collin
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 71:15-31
L'etude detaillee des processus d'ionisation des molecules d'acetylene et d'ethylene a ete entreprise au moyen d'un spectrometre de masse equipe d'une source d'electrons monoenergetiques. Certains processus d'apparition d'ions fragmentaires ont ete e
Autor:
Jacques E. Collin
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 62:411-427
After the analysis of the principal causes of error in appearance potential work, this paper deals with the determination of appearance potentials of a number of important ions of aliphatic amines as of ionisation potentials of theses substances. It
Autor:
E. De Pauw, Jacques E. Collin
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 87:589-593
The EPR spectra of N-substituted benzyl N-t-butyl nitroxides show a significant dependence of the β-CH2 proton hyperfine coupling constants on the position and the number of phenyl substituents. This behaviour may be explained by simple steric consi
Autor:
Jacques E. Collin
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 63:500-524
Different ways of approach have been proposed for the study of bond breakage probabilities under electron impact. The most interesting ones are calculation of stabilities, rupture coefficient and «indices de fragmentation», as proposed by Pahl, Via