Unveiling a key catalytic pocket for the ruthenium NHC-catalysed asymmetric heteroarene hydrogenation

Autor: Andrea Hamza, Daniel Moock, Christoph Schlepphorst, Jacob Schneidewind, Wolfgang Baumann, Frank Glorius

Publikováno v: Chemical science 13(4), 985-995 (2021). doi:10.1039/D1SC06409F

The chiral ruthenium(ii)bis-SINpEt complex is a versatile and powerful catalyst for the hydrogenation of a broad range of heteroarenes. This study aims to provide understanding of the active form of this privileged catalyst as well as the reaction me

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::07777452e03916a3746db7bc0757165d
https://doi.org/10.1039/d1sc06409f

Improving Selectivity and Activity of CO2 Reduction Photocatalysts with Oxygen

Autor: Henrik Junge, Jabor Rabeah, Vita A. Kondratenko, Evgenii V. Kondratenko, Stefanie Kreft, Matthias Beller, Roland Schoch, Jacob Schneidewind, Matthias Bauer, Sebastian Wohlrab

Publikováno v: Chem. 5:1818-1833

Summary A highly porous photocatalyst (copper on TiO2 aerogel) was synthesized and applied in aqueous CO2 reduction without using external sacrificial electron donors. For the first time, complete selectivity toward CO and improved catalyst productiv

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::358fa30bec1d90f061d1a537bf0ab948
https://doi.org/10.1016/j.chempr.2019.04.006

Two-photon, visible light water splitting at a molecular ruthenium complex

Autor: Matthias Beller, Henrik Junge, Jacob Schneidewind, Stefan Lochbrunner, Miguel A. Argüello Cordero

Publikováno v: Energy & environmental science 14(8), 4427-4436 (2021). doi:10.1039/D1EE01053K

Energy & environmental science 14(8), 4427-4436 (2021). doi:10.1039/D1EE01053K
Published by RSC Publ., Cambridge

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ba05e699f1c43e3de75c3da83843f958
https://doi.org/10.1039/d1ee01053k

Low-Temperature Hydrogenation of Carbon Dioxide to Methanol with a Homogeneous Cobalt Catalyst

Autor: Wolfgang Baumann, Ralf Jackstell, Rosa Adam, Jacob Schneidewind, Matthias Beller

Publikováno v: Angewandte Chemie. 129:1916-1919

Herein we describe the first homogeneous non-noble metal catalyst for the hydrogenation of CO2 to methanol. The catalyst is formed in situ from [Co(acac)3], Triphos, and HNTf2 and enables the reaction to be performed at 100 °C without a decrease in

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8b75c29a7f3a629526c75d55a560b599
https://doi.org/10.1002/ange.201609077

Simple ruthenium-catalyzed reductive amination enables the synthesis of a broad range of primary amines

Autor: Helfried Neumann, Jacob Schneidewind, Narayana V. Kalevaru, Rajenahally V. Jagadeesh, Matthias Beller, Kathiravan Murugesan, Wolfgang Baumann, Thirusangumurugan Senthamarai, Paul C. J. Kamer

Publikováno v: Nature Communications
Nature Communications, Vol 9, Iss 1, Pp 1-12 (2018)
Nature Communications 9(1), 4123 (2018). doi:10.1038/s41467-018-06416-6

The production of primary benzylic and aliphatic amines, which represent essential feedstocks and key intermediates for valuable chemicals, life science molecules and materials, is of central importance. Here, we report the synthesis of this class of

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1af5f9e04f532e893e93ae38bf8f70cd
http://europepmc.org/articles/PMC6175844