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Autor:
Dennis L. Lichtenberger, Orrasa In-noi, William P. Brezinski, Kenneth J. Haller, Jacob M. Marx, Gabriel B. Hall, Takahiro Sakamoto, Richard S. Glass, Dennis H. Evans
Publikováno v:
Organometallics. 33:5009-5019
The redox characteristics of (μ-SMe)2Fe2(CO)6 from the 1+ to 2– charge states are reported. This [2Fe-2S] compound is related to the active sites of [FeFe]-hydrogenases but notably without a linker between the sulfur atoms. The 1+ charge state was