Zobrazeno 1 - 3
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pro vyhledávání: '"Jacob G Robins"'
Autor:
Jacob G. Robins, Jeffrey S. Johnson
Publikováno v:
Org Lett
Progress toward a stereoselective synthesis of tetrodotoxin (TTX) is presented. Oxidative dearomatization of a tetrasubstituted guaiacol arene yielded a masked ortho-benzoquinone that intercepted an acyl nitroso species generated in situ by the coppe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f8c47abc791138ecbe344bd9fc61c62f
https://europepmc.org/articles/PMC8792300/
https://europepmc.org/articles/PMC8792300/
Publikováno v:
J Org Chem
The synthesis of the stereotriad core in the eastern portion of the Veratrum alkaloids jervine (1), cyclopamine (2), and veratramine (3) is reported. Starting from a known β-methyltyrosine derivative (8), the route utilizes a diastereoselective subs
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::de9ea09664450f480e09f54fe224e608
https://europepmc.org/articles/PMC7246867/
https://europepmc.org/articles/PMC7246867/
Publikováno v:
The Journal of Organic Chemistry. 81:2293-2301
A stereoselective intermolecular Diels–Alder cycloaddition of an intermediate pyrazinone with both achiral and chiral acrylate-derived dienophiles provides rapid access to the bicyclo[2.2.2]diazaoctane core shared among several prenylated indole al