Zobrazeno 1 - 10
of 286
pro vyhledávání: '"Jack Passmore"'
Autor:
Jack Passmore, T. Stanley Cameron, T. K. Whidden, Andreas Decken, Francis Arthur LeBlanc, J. Mikko Rautiainen
Publikováno v:
Inorganic Chemistry. 56:974-983
A convenient method for the preparation of strongly Lewis acidic tris-perfluoro-tert-butoxyborane B(ORF)3 (1), (ORF = OC(CF3)3) was developed, and its X-ray structure was determined. 1 was used as a precursor, guided by density functional theory (DFT
Autor:
Tressia A. P. Paulose, J. Mikko Rautiainen, Scott Greer, Andreas Decken, Melbourne J. Schriver, Friedrich Grein, Aaron Mailman, Jack Passmore, T. K. Whidden, Birgit Mueller, Stephanie Richardson
Publikováno v:
Inorganic Chemistry. 55:5999-6009
One mole equivalent of gaseous SO2 is absorbed by purple TDAE[O2SSO2](s), producing red, essentially spectroscopically pure TDAE[O2SS(O)2SO2](s); under prolonged evacuation, the product loses SO2(g), regenerating TDAE[O2SSO2](s). Similarly, [NR4]2[O2
Autor:
J. Mikko Rautiainen, Stephanie Richardson, Jack Passmore, Pablo J. Bruna, T. K. Whidden, Friedrich Grein, Andreas Decken
Publikováno v:
Inorganic Chemistry. 52:7193-7202
One mole equivalent of SO2 reversibly reacts with [N(CH3)4]2SO4(s) to give [N(CH3)4]2S2O6(s) (1) containing the [O3SOSO2]2–, shown by Raman and IR to be an isomer of the [O3SSO3]2– dianion. The experimental and calculated (B3PW91/6-311+G(3df)) vi
Autor:
Jack Passmore, Konstantin V. Shuvaev
Publikováno v:
Coordination Chemistry Reviews. 257:1067-1091
The current review provides up-to-date information on the structures, solution and solid state electron paramagnetic resonance (EPR), electronic and magnetic properties, and computational analysis of the novel 1,2,3,4-trithiazolium RCNSSS + radical c
Autor:
Andreas, Decken, Scott, Greer, Friedrich, Grein, Aaron, Mailman, Birgit, Mueller, Tressia A P, Paulose, Jack, Passmore, J Mikko, Rautiainen, Stephanie A, Richardson, Melbourne J, Schriver, Thomas K, Whidden
Publikováno v:
Inorganic chemistry. 55(12)
One mole equivalent of gaseous SO2 is absorbed by purple TDAE[O2SSO2](s), producing red, essentially spectroscopically pure TDAE[O2SS(O)2SO2](s); under prolonged evacuation, the product loses SO2(g), regenerating TDAE[O2SSO2](s). Similarly, [NR4]2[O2
Autor:
J. Mikko Rautiainen, Jack Passmore
Publikováno v:
European Journal of Inorganic Chemistry. 2012:6002-6010
1,3-Dimethyldisiloxane, O(SiH2Me)2, diethyl ether, OEt2, and their metal complexes (Li+,Ag+) have been used as model systems to uncover the reasons underlying the lower Lewis basicity of siloxanes compared to analogous ethers. Bonding in the metal co
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 638:744-753
Contact with SO2 causes almost immediate dissolution of tetraalkylammonium halides, R4NX, (R = CH3 (Me), X = I; R = C2H5 (Et), X = Cl, Br, I; R = C4H9 (nBu), X = Cl, Br), with the formation of an adduct, [R4N]+[(SO2)nX]– (n = 1–4). Vapor pressure
Publikováno v:
Inorganic Chemistry. 50:1491-1497
[18-Crown-6 Na](2)S(2)O(4) complex was prepared in methanol solution but dissociates into 18-Crown-6 ((s)) and Na(2)S(2)O(4 (s)) on removal of the solvent. Evidence for complexation in methanol is supported by a quantitative mass analysis and the dis
Publikováno v:
Journal of Fluorine Chemistry. 130:788-791
The O-2(+) ion is sufficiently similar in size to NO+ and so the difference in lattice energy in salts with a common anion can be expected to be negligible. Comparative analysis of O2F vs. NOF and of O-2(+) vs. NO+-salts is given in this paper and so
Autor:
Jack Passmore, Xinping Wang, Grigory B. Nikiforov, Carsten Knapp, J. Mikko Rautiainen, Andreas Decken, Xiaoqing Zeng
Publikováno v:
Chemistry - A European Journal. 15:6504-6517
Pushing the limits of coordination chemistry: The most weakly coordinated silver complexes of the very weakly coordinating solvents dichloromethane and liquid sulfur dioxide were prepared. Special techniques at low temperatures and the use of weakly