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pro vyhledávání: '"Jack A. Branch"'
Autor:
Jack A. Branch, Philip N. Bartlett
Publikováno v:
Journal of Electroanalytical Chemistry. 780:282-289
The voltammetry of decamethylferrocene, cobaltocene and decamethylcobaltocene at micro and macro disc electrodes in supercritical difluoromethane at 360 K and 17.6 MPa has been studied. In all cases the voltammetry is distorted to some degree by the
Publikováno v:
Electrochimica Acta. 187:323-328
We describe the assembly and characterisation of a reference electrode for use in supercritical difluoromethane (R32). The reference electrode is constructed from a europium doped lanthanum fluoride crystal contacted by silver loaded epoxy and encase
Autor:
Jack A. Branch, Philip N. Bartlett
Publikováno v:
Philosophical transactions. Series A, Mathematical, physical, and engineering sciences
A wide range of supercritical fluids (SCFs) have been studied as solvents for electrochemistry with carbon dioxide and hydrofluorocarbons (HFCs) being the most extensively studied. Recent advances have shown that it is possible to get well-resolved v
Publikováno v:
Physical chemistry chemical physics : PCCP. 17(1)
Detailed analysis of the voltammetry of decamethylferrocene at micro and macrodisc electrodes has been carried out in scCO2/MeCN (15 wt%), 20 mM [NBu(n)4][BF4] and 309 K and 17.5 MPa. A passivating film needs to be removed from platinum electrodes be