Zobrazeno 1 - 10
of 33
pro vyhledávání: '"JT Pinhey"'
Autor:
JT Pinhey
Publikováno v:
Australian Journal of Chemistry. 44:1353
Aryl-, vinyl- and alk-1-ynyl-lead(IV) tricarboxylates act as electrophilic arylating, vinylating and alkynylating agents, respectively, with a variety of nucleophiles, especially soft carbon nucleophiles such as β- dicarbonyl compounds, phenols and
Publikováno v:
Chemischer Informationsdienst. 9
Publikováno v:
Chemischer Informationsdienst. 9
The two heterocyclic compounds produced on irradiation of 3β-acetoxy-6- nitrocholest-5-ene (1) have been shown by chemical degradation to be 3β-acetoxycholest-4-eno[6,5,4-cd]isoxazole (3) and 3β-acetoxy-A- norcholestano[6,5-c]-2'-isoxazoin-5'-one
Publikováno v:
Tetrahedron Letters. 15:407-408
Publikováno v:
Australian Journal of Chemistry. 31:97
The photochemistry of 3β-acetoxy-6-nitrocholest-5-ene (1) and 6- nitrocholest-5-ene (11) has been investigated in a number of solvents. It is suggested that for both compounds the major primary photo-product is the corresponding aci-nitro tautomer,
Publikováno v:
Australian Journal of Chemistry. 37:1217
A detailed study of the photochemistry of a number of α-nitrostilbenes is reported. The previously described intramolecular cyclization of (1) which resulted in cleavage of the double bond was not found to occur to any extent in the other compounds
Publikováno v:
Australian Journal of Chemistry. 31:2563
Treatment of 6β-nitrocholest-4-ene with a catalytic amount of sodium methoxide in methanol gave an equilibrium mixture which contained the starting material and the 6α-epimer in a 1 : 1 ratio. The unusual stability of the 6β-epimer is explained by
Publikováno v:
Australian Journal of Chemistry. 31:113
The two heterocyclic compounds produced on irradiation of 3β-acetoxy-6- nitrocholest-5-ene (1) have been shown by chemical degradation to be 3β-acetoxycholest-4-eno[6,5,4-cd]isoxazole (3) and 3β-acetoxy-A- norcholestano[6,5-c]-2'-isoxazoin-5'-one
Publikováno v:
Australian Journal of Chemistry. 37:1231
The light-induced intramolecular cyclization of α, β-unsaturated nitro compounds leading to double bond cleavage, which had previously been detected in a small number of β-nitrostyrenes and α-nitro-stilbenes, has been shown to occur in a range of
Publikováno v:
Australian Journal of Chemistry. 38:1505
The photochemistry of cyclohexylidenenitromethane (6), 3-ethyl-2-nitropent-2-ene (7), (Z)-α-methyl-α- nitrostilbene (12), (E)-3-methyl- 1-nitro-1-phenylbut-1-ene (15) and 4,4-dimethyl-3-nitro-5α-cholest-2- ene (27) has been examined to determine t