Zobrazeno 1 - 10
of 150
pro vyhledávání: '"JOHN K. GILLHAM"'
Autor:
Armand F. Lewis, John K. Gillham
Publikováno v:
Journal of Polymer Science Part C: Polymer Symposia. 6:125-136
The application of the torsional braid technique to the thermal analysis of polymers (and monomers) is demonstrated. Included in this work are details of a visual method for estimating the dynamic mechanical damping factor of a freely oscillating sys
Autor:
John K. Gillham, Jong Keun Lee
Publikováno v:
Journal of Applied Polymer Science. 90:2665-2675
Isothermal physical ageing below the glass-transition temperature (Tg) of a high-Tg thermosetting difunctional epoxy/tetrafunctional aromatic amine system was investigated at different ageing temperatures (Ta) and chemical conversions (monitored by t
Publikováno v:
Journal of Applied Polymer Science. 81:396-404
The erasure below the glass-transition temperature (Tg) of the effect of isothermal physical aging (at aging temperature Ta) in a fully cured epoxy/amine thermosetting system is investigated using the torsional braid analysis (TBA) dynamic mechanical
Autor:
John K. Gillham
Publikováno v:
Polymer International. 44:262-276
Generalizations on the cure and properties of thermosetting polymers, which have stemmed from the development and application of the torsional braid analysis (TBA) technique, have been formulated in terms of cure–property relationships. They are th
Autor:
Shellee L. Maddox, John K. Gillham
Publikováno v:
Journal of Applied Polymer Science. 64:55-67
The rate and effects of isothermal physical aging of a fully cured epoxyamine/ glass fiber composite specimen were studied for a wide range of isothermal aging temperatures (-180 to 200°C) using a freely oscillating torsion pendulum technique: torsi
Autor:
Richard A. Venditti, John K. Gillham
Publikováno v:
Journal of Applied Polymer Science. 64:3-14
An equation, based on thermodynamic considerations to relate the glass transition temperature, T g , to compositional variation of a polymer system, is adapted in this article for modeling the T g vs. fractional conversion (x) relationship of reactiv
Publikováno v:
Journal of Applied Polymer Science. 64:27-38
A methodology is reported for monitoring the evolution of isothermal physical properties of thermosetting systems with increasing conversion (cure). For this report, measurements of modulus vs. temperature of a single composite specimen were obtained
Publikováno v:
Journal of Applied Polymer Science. 64:15-25
The present article describes a methodology for examining the evolution of the properties vs. cure of a complex thermosetting isocyanate/epoxy reactive mixture which reacts through two consecutive but separable reaction regimes. The methodology is ba
Autor:
John K. Gillham, Amy S. Vallely
Publikováno v:
Journal of Applied Polymer Science. 64:39-53
A single specimen of an epoxy/amine thermoset-glass fiber composite was examined, using a freely oscillating torsion pendulum operating at ∼ 1 Hz, for different conversions (as measured by T g ) from T g0 = 0°C to T gx = 184°C during cooling and
Autor:
Richard A. Venditti, John K. Gillham
Publikováno v:
Journal of Applied Polymer Science. 56:1687-1705
Isothermal properties of thermosetting materials after cure, such as density and modulus, pass through maximum and minimum values with increasing chemical conversion. In this report observed decreases in modulus and density at isothermal temperatures