Zobrazeno 1 - 10 of 11 pro vyhledávání: '"JACK KWIATEK"'
1
Reactions Catalyzed by Pentacyanocobaltate(II)
Autor: Jack Kwiatek
Publikováno v: Catalysis Reviews. 1:37-72
As early as a century ago Descamps[1] noted that solutions of cobaltous salts evolved hydrogen in the presence of cyanide ion. Yet it was not until 1942[2,3] that Iguchi observed that such solutions were able to absorb molecular hydrogen and transfer
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c3adbae703fae7167272ebaa37c22bde
https://doi.org/10.1080/01614946808064700
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2
Preparation of organocyanocobaltate(III) complexes
Autor: Jay K. Seyler, Jack Kwiatek
Publikováno v: Journal of Organometallic Chemistry. 3:421-432
Two methods have been found for the preparation of organocyanocobaltate(III) complexes. The first involves addition of [Co(CN) 5 H] 3- to activated olefins. The second involves reaction of [Co(CN) 5 ] 3- with organic halides. Studies show the mode of
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e547689342ff6ca412eb5cd556226ddf
https://doi.org/10.1016/s0022-328x(00)83570-6
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3
Protonation of organocyanocobaltate(III) complexes: A new synthesis of nitriles
Autor: Jack Kwiatek, Jay K. Seyler
Publikováno v: Journal of Organometallic Chemistry. 3:433-437
The protonation reactions of certain organocyanocobaltate(III) complexes have been studied. Complexes containing organic groups (R), where R = -C-CC or -C-CO, are cleaved to yield RH. Those containing organic groups (R′), where R′ = alkyl,
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a6167be33956e0cd234b8e71318bfdca
https://doi.org/10.1016/s0022-328x(00)83571-8
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8
Catalytic Hydrogenation by Pentacyanocobaltate(II): π- and σ- Allylic Complex Intermediates
Autor: Jay K. Seyler, Jack Kwiatek
Publikováno v: Proceedings of the 8th International Conference on Coordination Chemistry ISBN: 9783709136522
The catalytid hydrogenation of a variety of organic substrates may be effected by pentacyanocobaltate(II) anion in aqueous solution (1). A general requirement for the reduction of the carbon-carbon double bond is the presence of conjugation; thus, co
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::4d8df0f19acaf2641ac1243da8d573ee
https://doi.org/10.1007/978-3-7091-3650-8_117
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