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Interactions in the tri-n-butyl phosphate-water-diluent system

Autor: J.W. Roddy

Publikováno v: Journal of Inorganic and Nuclear Chemistry. 40:1787-1791

Tritium tracer techniques have been used to measure the solubility of water in undiluted TBP from 0 to 65°C at unit water activity and as a function of water activity at 25°C; from the latter results, the activity of the solvent has been derived by

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::92b5d04c04860a9f7c7fa000bda54b6a
https://doi.org/10.1016/0022-1902(78)80226-7

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Investigation of intermolecular association of 4-sec-butyl-2-(α-methylbenzyl)phenol (BAMBP) by use of dielectric and isopiestic measurements

Autor: J.W. Roddy, C.F. Coleman

Publikováno v: Journal of Inorganic and Nuclear Chemistry. 35:4271-4278

The association of the cesium extractant 4-sec-butyl-2-(α-methylbenzyl)phenol (BAMBP) in n-hexane was investigated by means of dielectric constant, density, refractive index and viscosity measurements at concentrations up to 6·85m and isopiestic me

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e4e0d730fd97dbda8eb80f716b9bb7be
https://doi.org/10.1016/0022-1902(73)80416-6

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The extraction of water by tri-n-octylamine and several of its salts in benzene and phenylcyclohexane

Autor: J.W. Roddy, C.F. Coleman

Publikováno v: Journal of Inorganic and Nuclear Chemistry. 31:3599-3611

The variation in water content of tri-n-octylamine (TOA) and several of its salts with water vapor pressure was determined by isopiestic and liquid-liquid equilibrium. In addition, the type of bonding was investigated with infrared absorption. Water

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::06743c63054a75768c9e517daf440f62
https://doi.org/10.1016/0022-1902(69)80348-9

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Mechanism of the slow extraction of iron(III) from acid perchlorate solutions by di(2-ethylhexyl)phosphoric acid in n-octane

Autor: J.W. Roddy, Sumio Arai, C.F. Coleman

Publikováno v: Journal of Inorganic and Nuclear Chemistry. 33:1099-1118

The rate of iron(III) extraction by di(2-ethylhexyl)phosphoric acid (HDEHP, HA) in n-octane from acid perchlorate solutions, as FeA3. 3HA, is controlled by series and parallel reactions in the introduction of the first and second anion ligands, all o

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c0084019c749c644bd9e510a7ac95315
https://doi.org/10.1016/0022-1902(71)80179-3

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Reference solutes for isopiestic and dynamic vapor pressure osmometry in organic solvents: Triphenylmethane, azobenzene, and benzil in dry benzene

Autor: J.W. Roddy, C.F. Coleman

Publikováno v: Journal of Inorganic and Nuclear Chemistry. 32:3891-3898

The vapor pressure lowering of benzene solutions of azobenzene (AZO), triphenylmethane (TPM), and benzil (BZL) was measured at 20°C by two methods, one a direct differential measurement of the difference between vapor pressures of solution and solve

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::2e29dae5bcd6d84b90b3bd41971b9ccf
https://doi.org/10.1016/0022-1902(70)80567-x

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The actinide hydrides: The americium-hydrogen system

Autor: J.W. Roddy

Publikováno v: Journal of Inorganic and Nuclear Chemistry. 35:4141-4148

Pressure-temperature-composition data and X-ray measurements were obtained to study the nature of the americium-hydrogen system using the long-lived americium-243 isotope ( t 1 2 = 7950 yr ). A Sievert's-type apparatus was employed to perform measure

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::14b30ddd6356536ef2ab604b1fc41d17
https://doi.org/10.1016/0022-1902(73)80401-4

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Activities and interaction in the Tri-n-butyl phosphate-water system

Autor: J.W. Roddy, J. Mrochek

Publikováno v: Journal of Inorganic and Nuclear Chemistry. 28:3019-3026

The solubility of water in TBP at 25°C and various water activities was measured by the isopiestic vapour balancing technique. The solubility follows Henry's law, XH2O = (0·478 ± 0·002)aH2O up to XH2O = 0·36 (CH2O = 1·2 M) at aH2O = 0·75, then

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::bad5014cdb40177d5864e0d4349c49eb
https://doi.org/10.1016/0022-1902(66)80029-5

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