Zobrazeno 1 - 10
of 37
pro vyhledávání: '"J.M. Pechine"'
Publikováno v:
Journal of Fluorine Chemistry. 86:149-153
The use of trifluoroacetic anhydride as an achiral derivatizing agent for enantiomeric excess measurement through chiral liquid crystal NMR is described. Examples involving amines, amino acids and alcohols are provided. It is shown that the proton de
Publikováno v:
Tetrahedron: Asymmetry. 8:485-494
The application of a ‘deuterium probe’ for the enantiomeric analysis of chiral amines, aminoacids and alcohols is proposed. The probe is the perdeuterated benzoyl fragment which can easily and reversibly be attached to the corresponding materials
Publikováno v:
Chem. Commun.. :1734-1735
Deuterium NMR in an aqueous non-chiral liquid crystal allows the discrimination of enantiomers through their ordering inside beta-cyclodextrins.
Publikováno v:
International Journal of Mass Spectrometry and Ion Physics. 25:7-25
The ionization and fragmentation of dimethyl and diethyl ether have been studied by means of photoionization at room temperature and low temperature. The parent ion thresholds show evidence of hot band effects, and the adiabatic ionization potentials
Publikováno v:
Tetrahedron. 38:1413-1416
Thermolysis at 800° of a series of β-keto-trimethylsilyl-enol-ethers allows the elimination of a trimethylsilanol molecule through a 1,5 rearrangement. The reaction products are furanic derivatives, which are obtained in often good yields through a
Publikováno v:
Journal of Electron Spectroscopy and Related Phenomena. 7:247-256
The photoelectron spectra of 6 dibromoalkanes and 9 bromofluoroalkanes have been recorded in the region of 10 to 11 eV, corresponding to the ionization of the n electrons of the bromine atom. For most of the compounds four peaks are observed. In the
Publikováno v:
International Journal of Mass Spectrometry and Ion Physics. 12:188-192
Autor:
J.M. Pechine
Publikováno v:
Organic Mass Spectrometry. 6:805-814
Les spectres de masse de 2,3-diphenylbutanes erythro et threo sont attribues a un rearrangement et a une rupture simple; leur calcul est propose. II est suggere que les differences entre les spectres des deux isomeres proviennent essentiellement de a
Publikováno v:
Organic Mass Spectrometry. 7:1287-1302
Les spectres de dix couples de bromures de cyclopentyle et de cyclohexyle α-substitues cis et trans sont enregistres pour onze energies d'ionisation distinctes comprises entre 10 et 20 eV. Pour chaque isomere un calcul du spectre de masse et de ses
Publikováno v:
Journal of Electron Spectroscopy and Related Phenomena. 13:141-143