Zobrazeno 1 - 10
of 22
pro vyhledávání: '"J.M. Gómez-Gil"'
Publikováno v:
DIGITUM. Depósito Digital Institucional de la Universidad de Murcia
instname
DIGITUM: Depósito Digital Institucional de la Universidad de Murcia
Universidad de Murcia
instname
DIGITUM: Depósito Digital Institucional de la Universidad de Murcia
Universidad de Murcia
Electrochemical reactions can effectively follow nonunity stoichiometries as can be found in the electrochemistry of halides, hydrogen and metal complexes. The voltammetric response of these systems shows peculiar deviations with respect to the well-
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4283eccba09554a30367d4f8578aacf0
http://hdl.handle.net/10201/105543
http://hdl.handle.net/10201/105543
Publikováno v:
The Journal of Physical Chemistry C. 121:26751-26763
Insights into ion pairing effects on the redox properties of the Keggin-type polyoxotungstate PW 12 O 40 3- are gained by combining electrochemical experiments and density functional theory (DFT) calculations. Such effects have been reported to affec
Publikováno v:
Journal of Solid State Electrochemistry. 20:3239-3253
Simple analytical expressions are deduced for the cyclic (staircase) and differential cyclic (staircase) voltammetric responses of the nine-member square scheme at the most widely used microelectrode geometries: disc, (hemi)spheres, cylinders and ban
Publikováno v:
Electrochimica Acta. 195:230-245
Using a diffusive-kinetic steady state theoretical treatment, a very simple analytical solution is deduced for the response of ECE-type processes at (hemi)spherical microelectrodes in normal pulse (NPV), derivative (DV) and steady-state voltammetries
Publikováno v:
Physical Chemistry Chemical Physics. 18:17091-17104
The study of the so-called aqueous complexation-dissociation coupled to transfer (ACDT) mechanism is extended to systems where the ligand species is not neutral and so the charge of the two transferable ions is different (z1 ≠ z2). This has a profo
Publikováno v:
Journal of Electroanalytical Chemistry. 873:114421
A general and easy-to-manage analytical theory is presented for the square wave voltammetry (SWV) of reversible electrode reactions with complex stoichiometry, aO + ne− ⇌ bR, at macroelectrodes valid for any value of the stoichiometric and diffus
Publikováno v:
Electrochimica Acta. 284
The monitoring of the non-interfacial phenomena of mass transport and homogeneous chemical reactions by combining spectroscopic and electrochemical methods is examined. The spectroelectrochemical study of a charge transfer process is addressed, consi
Analytical solutions are reported for the identification and study of homogeneous chemical reactions via UV–vis spectroelectrochemistry. Expressions are presented for the concentration profiles and the absorbance response of any the species of the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5ddfd6946fabf6b0c024c32f508442c3
https://doi.org/10.1016/j.jelechem.2017.10.031
https://doi.org/10.1016/j.jelechem.2017.10.031
Akademický článek
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Publikováno v:
Journal of Electroanalytical Chemistry. 847:113097
An analytical theoretical treatment of the first-order catalytic mechanism with non-Nernstian electron transfer is presented for electrodes of different geometry and size. As a result, a general and rigorous expression for the transient current-poten