Zobrazeno 1 - 10
of 115
pro vyhledávání: '"J.B. Stothers"'
Publikováno v:
Canadian Journal of Chemistry. 63:2401-2405
The photocycloaddition of allene to the steroidal enone 1a, normally occurring from the (less hindered) α side, has been directed in part to the (more hindered) β side by adsorption on the surface of silica gel. For a series of cyclic enone–allen
Publikováno v:
Phytochemistry. 15:855-872
The sesquiterpenes isolated from species of the Solanaceae under various conditions of stress are reviewed, with brief references to other solanaceous stress metabolites. The chemistry and selected physical properties of the sesquiterpenoidal compoun
Publikováno v:
Tetrahedron Letters. 22:509-512
Absorption spectroscopy of nitrites esters and carbonyl functions, and 13C chemical shifts of the carbonyl carbon, in substituted dodecanoate micelles appear to indicate the presence of a polar environment in the neighbourhood of the substituent.
Publikováno v:
Tetrahedron. 38:977-989
Pyrolysis of syn -2-adamantyl-4-d 1 methane-sulphonate 8 in a silanised pyrex reactor leads to protoadamantene with about 0.25 atoms 2 H at each of C-2, -7 and -9 and little labelling elsewhere according to 2 H and 13 C NMR. This indicates complete e
Publikováno v:
Tetrahedron Letters. 23:4465-4468
13Cmr spectra show complete absence of scrambling of an 18O label in 1 a recovered after partial conversion to 2 a thereby precluding an 0 -methylation mechanism for the bimolecular formation of 2 a from 1 a .
Autor:
A. Stoessl, J.B. Stothers
Publikováno v:
Canadian Journal of Chemistry. 53:3359-3364
The reaction of 2-furfurylidene-10-methyl-trans-1-decalone with base (NaOH – aqueous HOCH2CH2OH) has been reinvestigated and found to give nine products. Elucidation of the structures of eight of these products, which accounted for ca. 80% of the p
Publikováno v:
Tetrahedron. 20:913-928
An intercomparison of the NMR data for the methyl protons in a series of thirty-seven alkaloids of the Veratrum group provides additional support for previous proposals regarding the β-configuration of the C-27 methyl group in all of these compounds
Publikováno v:
Canadian Journal of Chemistry. 50:612-617
The structure of the dimer formed from acetonylacetone and hydrazine has been re-examined. On the basis of chemical and spectroscopic data, a covalent tricyclic structure is proposed.
Publikováno v:
Canadian Journal of Chemistry. 39:488-497
The irradiation of dialkyl ketones in cyclohexene leads to the formation of cyclohexenyl-dialkylcarbinols. The use of aldehydes leads to the formation of the corresponding secondary alcohols, but the reaction is more complex because of concomitant Kh
Publikováno v:
Tetrahedron. 21:1417-1432
The mixture of ergot pigments from a Portuguese ergot drug has been separated. Aside from ergoflavin five other pigments have been characterized and structural proposals for four of these made.