Zobrazeno 1 - 10 of 25 pro vyhledávání: '"J. W. Rathke"'
1
Reversible Hydrocarbon Activation by Rhodium Phthalocyanine Dimer [(R8Pc)Rh]2 (R8Pc2- = Dianion of 1,4,8,11,15,18,22,25-Octa-n-pentylphthalocyanine)
Autor: J. W. Rathke, M. J. Chen
Publikováno v: Organometallics. 13:4875-4880
We have synthesized four rhodium-phthalocyanine complexes: (R[sub 8]Pc)(C[sub 6]H[sub 5]CN)CIRh, [(R[sub 8]-Pc)(MeOH)[sub 2]Rh]Cl, [(R[sub 8]Pc)Rh][sub 2](1), and (R[sub 8]PcH)RhRh(R[sub 8]Pc)H (2). In this notation R[sub 8]Pc[sup 2[minus]] is the di
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0476f85e754ab89d521c05c59fe679c9
https://doi.org/10.1021/om00024a033
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2
High-Pressure NMR Investigation of Hydrogen Atom Transfer and Related Dynamic Processes in Oxo Catalysis
Autor: J. W. Rathke, R. J. Klingler
Publikováno v: Journal of the American Chemical Society. 116:4772-4785
The cobalt center in HCo(CO)[sub 4] exchanges with those in Co[sub 2](CO)[sub 8] through a facile hydride ligand transfer reaction which has been studied by [sup 59]Co NMR line-shape analysis over the temperature range of 80 to 200[degree]C and total
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1c8f046569f53eb29d6ac213ad7e7415
https://doi.org/10.1021/ja00090a025
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3
Peripherally Substituted Phthalocyanines
Autor: M. J. Chen, Donald W. Slocum, J. W. Rathke, S. Sinclair
Publikováno v: Journal of Macromolecular Science, Part A. 27:1415-1430
Peripherally substituted phthalocyanine (Pc) systems render more accessible the desirable properties of the Pc system, i.e., high thermal and oxidative stability as well as significant complexity ability of transition metals. After brief examination
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d250a8a309b6f504a681cff1645e98a4
https://doi.org/10.1080/10601329008544849
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5
Dynamics of room-temperature melts: nuclear magnetic resonance measurements of dialkylimidazolium haloaluminates
Autor: Mo Chen, Setsuko Takahashi, Marie-Louise Saboungi, J. W. Rathke, R. J. Klingler
Publikováno v: Journal of the Chemical Society, Faraday Transactions. 89:3591
The room-temperature molten salts formed by combining AlCl3 with 1-ethyl-3-methylimidazolium chloride (EMIC) have been investigated by 27Al and 35Cl NMR spectroscopy at temperatures from 25 to 100 °C. The initial AlCl3 loading was varied from 50 mol
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::369785a1efe26de130f87f68455476d0
https://doi.org/10.1039/ft9938903591
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8
Catalysis of carbon monoxide hydrogenation by soluble mononuclear complexes
Autor: H. M. Feder, J. W. Rathke
Publikováno v: Journal of the American Chemical Society. 100:3623-3625
The homogeneous hydrogenation of CO to CH/sub 3/OH, higher primary alcohols and their formate esters in the presence of Co/sub 2/(CO)/sub 8/ using benzene, heptane, and p-dioxane as solvents is reported. The principal rate-determining step is first o
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f752549fbc410e3604fb3cea6c987fe3
https://doi.org/10.1021/ja00479a069
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10
ChemInform Abstract: CHEMISTRY OF PENTAKIS(TRIMETHYL PHOSPHITE)IRON(0), (FE(P(OME)3)5)
Autor: J. W. Rathke, E. L. Muetterties
Publikováno v: Chemischer Informationsdienst. 6
A new zerovalent iron complex,[Fe{P(OMe)3}5], has been prepared; this volatile molecule has a relatively basic iron atom that is readily protonated and alkylated.
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::565953bea4bedf2e98996fe5c44804b5
https://doi.org/10.1002/chin.197504378
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