Zobrazeno 1 - 10
of 116
pro vyhledávání: '"J. V. Michael"'
Autor:
L. N. Krasnoperov, J. V. Michael
Publikováno v:
The Journal of Physical Chemistry A. 108:8317-8323
The reflected shock tube technique with multipass absorption spectrometric detection has been used to study the reactions of OH radicals: (1) OH + CH 3 → 1 CH 2 + H 2 O, (2) OH + 3 CH 2 → CH 2 O + H, and the thermal dissociation of methanol, (3)
Autor:
Lev N. Krasnoperov, J. V. Michael
Publikováno v:
The Journal of Physical Chemistry A. 108:5643-5648
The reflected shock tube technique with a novel multipass absorption spectrometric detection method has been used to study two OH-radical reactions: OH + H2 → H2O + H (1), and OH + C2H6 → H2O + C2...
Autor:
J. V. Michael, S. S. Kumaran
Publikováno v:
Combustion Science and Technology. 134:31-44
Thermal decomposition results for CCl 4 , CHCl 3 , CH 2 Cl 2 , CH 3 Cl, C 3 H 3 Cl, CFCl 3 , CF 2 Cl 2 , CF 3 Cl, CF 2 HCl, CF 3 I, CH 3 I, C 2 H 5 I, C 6 H 5 I, and CCl 2 O are reviewed and summarized. The results were obtained by shock tube techniq
Autor:
S. S. Kumaran, J. DiFelice, K. P. Lim, and J. V. Michael, Albert F. Wagner, Meng-Chih Su, David A. Dixon, J. H. Kiefer and
Publikováno v:
The Journal of Physical Chemistry. 100:15827-15833
The development of a multipass optical absorption (MPA) technique for detecting CF2 radicals behind reflected shock waves and its application for studying the thermal dissociation of CF2HCl in Kr a...
Publikováno v:
Review of Scientific Instruments. 66:4649-4654
An UV multipass optical absorption method to increase the sensitivity for radical species detection has been developed for high temperature chemical kinetics experiments in a shock tube. The specific illustration is for OH radicals in the reflected s
Publikováno v:
The Journal of Chemical Physics. 101:9487-9498
Rate constants for the Cl+H2 and D2 reactions have been measured at room temperature by the laser photolysis‐resonance absorption (LP‐RA) technique. Measurements were also performed at higher temperatures using two shock tube techniques: laser ph
Publikováno v:
The Journal of Physical Chemistry. 98:12278-12283
The unimolecular decomposition CF[sub 3]Cl + Kr [yields] CF[sub 3] + Cl + Kr has been studied using two different techniques, atomic resonance absorption spectrometry (ARAS) and laser schlieren (LS) density gradients, in two laboratories. As in our p
Publikováno v:
The Journal of Physical Chemistry. 98:8411-8418
The thermal bimolecular rate coefficients, O + CH[sub 2]Cl[sub 2] and O + CHCl[sub 3], have been investigated in this work over the respective temperature ranges 468-1355 and 499-1090 K using two entirely different techniques. The first technique, HT
Autor:
J. V. Michael, K. P. Lim
Publikováno v:
The Journal of Physical Chemistry. 98:211-215
The thermal decomposition of COCl[sub 2] has been studied in incident shock waves at three different loading pressures and varying [COCl[sub 2]][sub 0]. The kinetics experiments were performed at temperatures between 1400 and 2000 K by monitoring the
Autor:
K. P. Lim, J. V. Michael
Publikováno v:
Annual Review of Physical Chemistry. 44:429-458