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Publikováno v:
Journal of Molecular Spectroscopy. 215:134-143
The far-infrared torsional spectrum of CH 3 SiD 3 has been measured in a continuing effort to quantify the coupling between the small amplitude vibrations and the large amplitude internal rotation of the methyl group in symmetric tops. It is hoped th
Autor:
Veli-Matti Horneman, Nasser Moazzen-Ahmadi, E. A. Alekseev, S.-X. Wang, S.F. Dyubko, V.V. Ilyushyn, J. Schroderus, Irving Ozier, A.A. Katrich
Publikováno v:
Journal of Molecular Spectroscopy. 214:69-79
An investigation of the torsion–rotation–vibration energies in the ν 5 vibrational state in CH 3 CF 3 has been carried out using infrared and mm-wave spectroscopy. The lowest frequency parallel fundamental band ν 5 near 600 cm −1 has been mea
Publikováno v:
Journal of Molecular Structure. 599:69-79
The analysis of the high resolution FTIR spectra and the diode laser spectra of the ν 1 0 (E')/2ν 1 4 (A' 1 ⊕ E') dyad of 1 2 C 3 1 4 N 3 H 3 , 1 2 C 3 1 5 N 3 H 3 and 1 3 C 3 1 4 N 3 H 3 is reported. The components of this dyad are found to form
Publikováno v:
Journal of Molecular Spectroscopy. 209:228-232
The far-infrared spectrum of gaseous CH3CH3 has been measured at a resolution of 0.0016 cm−1 using a Fourier transform spectrometer. The spectrum was recorded with an absorption pathlength of 172 m. The temperature and pressure of the sample were 2
Publikováno v:
The Journal of Chemical Physics. 115:1392-1404
The lowest frequency parallel fundamental band ν5 of CH3SiH3 near 700 cm−1 has been measured at a resolution of 0.004 cm−1 with Fourier transform spectroscopy to investigate vibration–torsion–rotation interactions in symmetric tops. The tors
Publikováno v:
Evolutionary Ecology. 15:443-462
Publikováno v:
Journal of Molecular Spectroscopy. 200:1-15
High-resolution Fourier transform infrared spectrum of CH(3)D has been recorded in the region of the fundamental bands nu(3), nu(5), and nu(6) between 900 and 1700 cm(-1). High sensitivity of the equipment used as well as high accuracy of the recorde
Publikováno v:
Journal of Molecular Structure. :25-40
The high-resolution Fourier transform spectra of the CHD3 molecule have been recorded and assigned between 1850 and 2450 cm−1. To verify the assignments and to span a more complete energy manifold in the excited vibrational states, the hot bands 2
Publikováno v:
The Journal of Chemical Physics. 111:9609-9617
Fourier transform measurements of the lowest frequency degenerate fundamental band of CH3CH3 (v9=1←0) in the 12-μm region together with far-infrared torsional spectra have been analyzed to investigate vibration–torsion–rotation effects in a sy