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Publikováno v:
Chemischer Informationsdienst. 7
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :1169
Caged phosphite complexes of the type [MH{P(OCH2)CPrn}4](M = Co, Rh, or Ir) have been synthesized. These complexes are stereochemically non-rigid on the n.m.r. time scale at 25 °C. However, for the rhodium and iridium analogues, near-limiting and li