Zobrazeno 1 - 10
of 20
pro vyhledávání: '"J. Oeschger"'
Publikováno v:
Journal of the American Chemical Society. 144(23)
We report an experimental study, with accompanying DFT calculations, on a series of heterobimetallic complexes with Pd(II) and Cu(I), Ag(I), or Au(I). The isolable pincer complexes are models for the intermediates and transition state for the transme
Autor:
Sam He, Isaac Yu, Erik A. Romero, Raphael J. Oeschger, Christian Ehinger, John F. Hartwig, Bo Su
Publikováno v:
Science
Speeding up borylation Catalytic borylation is the rare reaction that can selectively target stronger over weaker saturated carbon–hydrogen (C–H) bonds. However, the trade-off has been that the reaction is slow and requires high excess of the hyd
Publikováno v:
ACS Catal
ACS catalysis, vol 10, iss 5
ACS catalysis, vol 10, iss 5
An in-depth study of iridium catalysts for the borylation of alkyl C-H bonds is reported. Although the borylation of aryl C-H bonds can be catalyzed by iridium complexes containing phen or bpy ligands at mild temperatures and with limiting arene, the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7c7055c7ad273e2a8c9ef89c8093465a
https://europepmc.org/articles/PMC7654975/
https://europepmc.org/articles/PMC7654975/
Autor:
Peter Chen, Raphael J. Oeschger
Publikováno v:
Organometallics. 36:1465-1468
A heterobimetallic Pd(II)–Zn(II) complex has been prepared and characterized by X-ray diffraction analysis. An accompanying computational study shows that the bimetallic complex is predominantly stabilized by a short metal–metal bond; ΔG for the
Publikováno v:
J Am Chem Soc
A mechanistic study on the origin of the difference in reactivity between Ir catalysts for C−H borylation reactions is reported. Catalytic reactions of B(2)pin(2) with a series of substrates that require high temperatures and long reaction times we
Publikováno v:
Organometallics. 34:3888-3892
The microscopic reverse of the transmetalation step in the Pd/M (M = Cu, Ag, Au) catalyzed Sonogashira-type reactions has been observed in the gas phase upon collision-induced dissociation (CID) of the heterobimetallic complexes. Measuring the activa
Autor:
Raphael J. Oeschger, Peter Chen
Publikováno v:
Journal of the American Chemical Society. 139(3)
A heterobimetallic Pd(II)/Cu(I) complex was prepared and characterized by X-ray diffraction analysis. The crystal structure shows a remarkably short Pd–Cu bond and a trigonal ipso carbon atom. The Pd–Cu interaction, as determined by energy-resolv
Publikováno v:
OCEANS 2008.
There is a pressing need for a practical and effective magnetic sensing technology that can be deployed onboard highly maneuverable sensing platforms and used for real-time, point-by-point detection, localization and classification (DLC) of magnetic
Autor:
J. Oeschger, R. Wiegert
Publikováno v:
Proceedings of OCEANS 2005 MTS/IEEE.
We report significant progress toward full development of a unique magnetic-gradient-tensor-based "scalar triangulation and ranging (STAR)" method for detection, localization and classification (DLC) of magnetic targets. The STAR method converts magn
Publikováno v:
Organometallics; Aug2015, Vol. 34 Issue 15, p3888-3892, 5p