Iminophosphanes: Synthesis, Rhodium Complexes, and Ruthenium(II)-Catalyzed Hydration of Nitriles

Autor: Jeroen J. M. de Pater, Mark K. Rong, Andreas W. Ehlers, Berth-Jan Deelman, Martin Nieger, Tom van Dijk, J. Chris Slootweg, Koen Van Duin, Koop Lammertsma

Publikováno v: Rong, M K, Van Duin, K, Van Dijk, T, De Pater, J J M, Deelman, B J, Nieger, M, Ehlers, A W, Slootweg, J C & Lammertsma, K 2017, ' Iminophosphanes : Synthesis, Rhodium Complexes, and Ruthenium(II)-Catalyzed Hydration of Nitriles ', Organometallics, vol. 36, no. 5, pp. 1079-1090 . https://doi.org/10.1021/acs.organomet.7b00057
Organometallics, 36(5), 1079-1090. American Chemical Society
Organometallics
Organometallics, 36(5), 1079. American Chemical Society

Highly stable iminophosphanes, obtained from alkylating nitriles and reaction of the resulting nitrilium ions with secondary phosphanes, were explored as tunable P-monodentate and 1,3-P,N bidentate ligands in rhodium complexes. X-ray crystal structur

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7df6e6a681588a98619d6f83cd46ccbe
https://doi.org/10.1021/acs.organomet.7b00057

Lightly fluorous [Pd(OAc)2{P(C6H4-p-SiMe2CH2CH2C6F13)3}2] in the methoxycarbonylation of styrene: Formation, performance and stability of the catalyst system

Autor: Cornelis J. Elsevier, Berth-Jan Deelman, Jeroen J. M. de Pater, Gerard van Koten

Publikováno v: Journal of Molecular Catalysis A-Chemical, 258(1-2), 334-340. Elsevier

The fluorous palladium(II) complex, [Pd(OAc)2{P(C6H4-p-SiMe2CH2CH2C6F13)3}2], has been prepared and characterized. Its application in the catalytic methoxycarbonylation of styrene in an MeOH/CF3C6H5 mixture (1/1 v/v) has been explored and its activit

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::839ebe67f3c83676ca44f37d3c527c69
https://doi.org/10.1016/j.molcata.2006.05.052

Novel enantiopure non-C2-symmetric NCN-pincer palladium complexes with l-proline chiral auxiliaries: mer η3-N,C,N versus square planar η4-N,C,N,O coordination

Autor: Silvia Gosiewska, Gerard van Koten, Martin Lutz, Anthony L. Spek, Jeroen J. M. de Pater, Robertus J. M. Klein Gebbink, Marije H. Huis in ‘t Veld, Pieter C. A. Bruijnincx

Publikováno v: Tetrahedron: Asymmetry. 17:674-686

New chiral NCN-pincer palladium complexes containing proline ester moieties as chiral auxiliaries have been synthesized. The parent ligands 2,6-bis{[(S)-2-(methoxycarbonyl)-1-pyrrolidinyl]methyl}-1-bromobenzene LMe and 2,6-bis{[(S)-2-(benzoxycarbonyl

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e9650f3a7a0c6149c5667917a323255c
https://doi.org/10.1016/j.tetasy.2005.12.040

Striking Facial Dysmorphisms and Restricted Thymic Development in a Fetus with a 6-Megabase Deletion of Chromosome 14q

Autor: C. J. M. van der Sijs-Bos, M. J. Eleveld, Martin Poot, J. M. de Pater, W. H. Loneus, J. J. M. Engelen, P. G. J. Nikkels, R. H. Stigter

Publikováno v: Pediatric and Developmental Pathology. 8:497-503

During routine ultrasound screening at 12 weeks 5 days of gestation, a nuchal translucency of 7 mm, an omphalocele, and fetal hydrops were found and prompted chorionic villus sampling at 13 weeks 2 days. Chromosome analysis showed an unbalanced karyo

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b2f57e3039edf36f54eecfa407e5852e
https://doi.org/10.1007/s10024-005-0041-8

Mosaic trisomy (8)(p22 ? pter) in a fetus caused by a supernumerary marker chromosome without alphoid sequences

Autor: M. Verschuren, H. Y. Kroes, J. M. de Pater, J. C. M. Albrechts, A. C. C. van Oppen, John J.M. Engelen

Publikováno v: Prenatal Diagnosis. 25:151-155

Objective Our objective was to characterise a marker chromosome in cultured amniocytes of a fetus with a mos 47,XX,+mar[3]/46,XX[14] karyotype. Methods The indication for prenatal cytogenetic analysis of cultured amniocytes was advanced maternal age.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f3b0ba343f56e072f841590e483f9e88
https://doi.org/10.1002/pd.1097