Zobrazeno 1 - 10
of 168
pro vyhledávání: '"J. Levisalles"'
Autor:
Et J. Levisalles, L. Dehennin
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 85:333-345
The formation of heptafluorobutanoic esters of some steroidal alcohols, phenol and conjugated ketone was described. The kinetic study of these reactions in presence of acid showed a hyperbolic relationship between kexp and the acid concentration for
Publikováno v:
Tetrahedron. 54:5287-5304
Synthesis of p -toluenesulfonates 8b and 9b and of labelled analogs is described and previous assignements of proton NMR signals for quaternary methyl groups are confirmed. Acetolysis of these p -toluenesulfonates in the presence of NaOAc gave both s
Autor:
Martin Weissenberg, J. Levisalles
Publikováno v:
Tetrahedron. 51:5711-5742
Publikováno v:
Tetrahedron. 49:7679-7690
Resume Les etats de transition de differents processus thermiques (elimination, rearrangement sigmatropique) ont ete evalues par la methode AM1. Le processus de rearrangement sigmatropique est le plus favorise et l'etat de transition bateau est plus
Autor:
Martin Weissenberg, J. Levisalles
Publikováno v:
ChemInform. 26
Autor:
Didier Villemin, J. Levisalles
Publikováno v:
Tetrahedron. 36:3181-3185
Esters of alkenoic acids, including insect pheromones as examples, have been synthesized using alkene metathesis reactions.
Publikováno v:
Journal of Organometallic Chemistry. 177:239-244
Treating (CO)5WC(Ph)Ph with cyclic enol ethers in n-hexane, leads, in the case of the cyclopentanone derivative, to ring-opened product (CO)5WC(OEt)[(CH2)3CHC(Ph)Ph] which has been isolated and characterized. The ring size in the enol ether
Publikováno v:
Tetrahedron. 39:103-115
Absolute rates of bromination were measured for two series of derivatives of steroidal ketones 3, enol acetates 1 and enol methyl ether 2. Axial substituents exhibited a large effect on rates, which increased by 15,000 fold on going from (X=CH3; Y=CN
Publikováno v:
Journal of Organometallic Chemistry. 187:233-242
The reaction of MeLi with MeOC(Me)W(CO) 5 (I) gives an unexpected binuclear complex [(CO) 4 W] 2 HCCHC(Me) 2 (II), the X-ray structure which shows a very short HCCH bond. A mechanism for the formation of II is outlined.
Publikováno v:
Organic Magnetic Resonance. 10:192-197
Isoles et identifies, vingt-cinq chlorures vinyliques ont ete caracterises par resonance magnetique du proton (RMN 1H), par chromatographie en phase vapeur (CPV) et, pour certains, par voie chimique. De nouveaux increments specifiques du groupe alkyl