Zobrazeno 1 - 10
of 86
pro vyhledávání: '"J. Hodge Markgraf"'
Publikováno v:
Journal of Heterocyclic Chemistry. 46:1318-1323
Publikováno v:
Magnetic Resonance in Chemistry. 45:985-988
The synthesis and assignment of 15N and 13C NMR signals of the 1,3,4-oxathiazol-2-one ring in a series of para-substituted 5-phenyl derivatives are reported. DFT calculations of 15N and 13C chemical shifts correspond closely to observed values. Subst
Publikováno v:
Tetrahedron. 56:5329-5335
Concise and efficient routes to the carboline alkaloids isocanthine (3), isocanthin-6-one (4), 1-methylisocanthine (5), and 1-methylisocanthin-6-one (6) are reported. In each case, the key synthetic step was an intramolecular hetero Diels–Alder rea
Autor:
Bo Yoon Choi, J. Hodge Markgraf
Publikováno v:
Synthetic Communications. 29:2405-2411
A convenient procedure for the oxidation of benzyl ethers to benzoate esters is reported. Potassium permanganate in dichloromethane with phase transfer catalysis by triethylbenzylammonium chloride (TEBAC) affords products regiospecifically in fair to
Autor:
J. Hodge Markgraf, John R. Cort, Manuel Finkelstein, Raymond Chang, Raymond C. Petersen, Michael H. Lavyne, Sidney D. Ross, C.Michael Moore, J. L. Durant, Andrew W. Gross
Publikováno v:
Tetrahedron. 53:10009-10018
The protodediazoniation of aryldiazonium fluoroborates can be effected by warm dimethylformamide (DMF). The conversion of 4-nitrobenzenediazonium fluoroborate to nitrobenzene was studied in detail. Products derived from trapping experiments were cons
Publikováno v:
Synthetic Communications. 27:1285-1290
A convenient method for the conversion of tertiary benzylamines to benzamides by phase transfer oxidation is described. Yields are good. Regioselectivities are reported.
Publikováno v:
Tetrahedron. 52:461-470
Carbocyclic analogs ( 10 and 12 ) of canthine ( 1 ) and canthin-6-one ( 2 ) were prepared in three and four steps, respectively, from indole-3-car☐aldehyde. The key step was an intramolecular Diels-Alder reaction carried out in refluxing sulfolane.
Autor:
J. Hodge Markgraf, Bo Yoon Choi
Publikováno v:
ChemInform. 30
A convenient procedure for the oxidation of benzyl ethers to benzoate esters is reported. Potassium permanganate in dichloromethane with phase transfer catalysis by triethylbenzylammonium chloride (TEBAC) affords products regiospecifically in fair to
Autor:
J. Hodge Markgraf, Carolyn A. Stickney
Publikováno v:
ChemInform. 31
The synthesis of N-phenyl lactams by phase transfer oxidation of N,N-(polymethylene) anilines with potassium permanganate is reported.
Publikováno v:
ChemInform. 31
Concise and efficient routes to the carboline alkaloids isocanthine (3), isocanthin-6-one (4), 1-methylisocanthine (5), and 1-methylisocanthin-6-one (6) are reported. In each case, the key synthetic step was an intramolecular hetero Diels–Alder rea