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ChemInform Abstract: Reactions of Benzo(b)thiophene with Some Aqueous Platinum Metal Species at Elevated Temperatures

Autor: Martin J. Kirk, J. F. Fait, C. G. Jones, Peter D. Clark

Publikováno v: ChemInform. 22

The desulfurization of benzo[b]thiophene 1 with aqueous transition metal species in the presence of various hydrocarbons at elevated temperatures is described. Mechanistic studies have shown that treatment of 1 with solutions of RuCl3 and other plati

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::54d4da1aa70093d5d9f8030ed4f0e575
https://doi.org/10.1002/chin.199139108

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ChemInform Abstract: Preparation and Solid-State Isomerization of Se,Se′- Dialkyltetraphenyldiphosphadiselenatetrazocines: X-Ray Structures of 1, 5-Ph4P2N4Se2Me2 and (Ph2P(NH2)2)2Se

Autor: J. F. Fait, Daniel D. Doxsee, Masood Parvez, Tristram Chivers

Publikováno v: ChemInform. 24

The reaction of the Ph 2 PN 2 (SiMe 3 ) 3 with organoselenium trichlorides RSeCl 3 in acetonitrile at 23 o C produces high yields of 1,5-Ph 4 P 2 N 4 Se 2 R 2 (1a, R=Me; 1b, R=Et; 1c, R=Ph) and, for 1a,b, small amounts of 1,5-Ph 4 P 2 N 4 Se 2 . Thes

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::6e491e2c147381647441e0ac3c375143
https://doi.org/10.1002/chin.199338277

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Reactions of benzo[b]thiophene with some aqueous platinum metal species at elevated temperatures

Autor: J. F. Fait, Martin J. Kirk, C. G. Jones, Peter D. Clark

Publikováno v: Canadian Journal of Chemistry. 69:590-598

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a22f4008e95fe0883cda34bce5fb3988
https://doi.org/10.1139/v91-089

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Carbon tetrachloride–thiourea (1/3) adduct at 170 K

Autor: C. N. Caughlan, J. F. Fait, F. P. McCandless, A. Fitzgerald

Publikováno v: Acta Crystallographica Section C Crystal Structure Communications. 47:332-337

CCl 4 •3CH 4 N 2 S cristallise dans R3 avec a=15,539, c=12,529 A, Z=18, T=170 K; affinement jusqu'a R=0,043. Le carbone de la molecule CCl 4 desordonnee est coplanaire avec les trois atomes S de la thiouree. Il apparait des interactions de Coulomb

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8febeb6e8b96f7c8fb500dee95e13718
https://doi.org/10.1107/s0108270190004577

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mer-Trichlorotris(2,3-dihydrobenzo[b]thiophene-S)rhodium(III)

Autor: J. F. Fait, Peter D. Clark, C. G. Jones, Masood Parvez

Publikováno v: Acta Crystallographica Section C Crystal Structure Communications. 49:383-385

The Rh atom has a distorted octahedral geometry. Two of the benzothiophenyl ligands occupy trans equatorial positions with Rh-S distances [2.351 (1) and 2.369 (1) A] which are significantly longer than the third [2.330 (1) A] distance. The Rh-Cl dist

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::57b3fe6af2e03afafd09c8bf1dfd954d
https://doi.org/10.1107/s0108270192009545

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Structure of (CO)5Cr[P(Me3SiNH)NSNSNH]: the chromium pentacarbonyl complex of a PIIIN3S2 ring

Autor: J. F. Fait, C. Lensink, Tristram Chivers

Publikováno v: Acta Crystallographica Section C Crystal Structure Communications. 46:131-133

[Cr(CO) 5 (C 3 H 11 N 4 PS 2 Si)] cristallise dans P2 1 /n avec a=6,266, b=13,739 et c=19,959 A, β=101,97 o , Z=4; affinement jusqu'a R=0,065. La molecule est un complexe octaedrique dans lequel Cr(CO) 5 occupe la position axiale sur l'atome P d'un

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7332f05278dd1c8ff58e616d0e5b0dba
https://doi.org/10.1107/s0108270189008590

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