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pro vyhledávání: '"J. Claire Stott"'
Publikováno v:
Dalton Trans.. :3788-3797
The tetrahydroborate ligand in [Ru(eta(2)-BH(4))(CO)H(PMe(2)Ph)(2)], 1, allows conversion under very mild conditions to [Ru(CO)(Et)H(PMe(2)Ph)(3)], 7, by way of [Ru(eta(2)-BH(4))(CO)Et(PMe(2)Ph)(2)], 4. Deprotection of the hydride ligand in 7(by BH(3
Publikováno v:
Dalton Trans.. :2603-2614
Reaction of [Ru(CO)(η3-C3H5)Cl(PMe2Ph)2], 1, with CO and Ag+ yielded 2A and 2B, isomers of [Ru(CO)2(η3-C3H5)(PMe2Ph)2]+. Treatment of 2B with BH4− gave [Ru(CO)2(CH2CH2CH2)(PMe2Ph)2], 7, and [Ru(η2-BH4)(CO)H(PMe2Ph)2], 6, subsequently obtained fr
Publikováno v:
Dalton Transactions: An International Journal of Inorganic Chemistry; Jun2003, Vol. 2003 Issue 12, p2603-2614, 12p