Zobrazeno 1 - 10
of 27
pro vyhledávání: '"J. Ben H. Jansen"'
Publikováno v:
Clays and Clay Minerals. 45:1-7
The effects of reaction time (2 to 72 h) and NH (super +) 4 /Al (super 3+) molar ratio (1.6, 2.4 and 3.2) on the hydrothermal synthesis of ammonium-saponites are investigated. The gels are obtained by mixing powders, resulting in a stoichiometric com
Autor:
Don Seykens, J. Ben H. Jansen, Roland J. M. J. Vogels, Paul A. Buining, John W. Geus, J. Theo Kloprogge
Publikováno v:
Journal of Non-Crystalline Solids. 191:38-44
The aging of the aluminum tridecamer in acidified aluminum sec-butoxide is studied with 27Al nuclear magnetic resonance. At 20°C the tridecamer content passes through a maximum of 19.7% after 133 h of aging to decline subsequently to a final content
Autor:
Ronald J. Bakker, J. Ben H. Jansen
Publikováno v:
Contributions to Mineralogy and Petrology. 116:7-20
Preferential leakage of H2O from fluid inclusions containing multiple gas components has been suspected in natural metamorphic rocks and has been demonstrated experimentally for synthetic H2O-CO2-rich inclusions in natural quartz. Knowledge of the ph
Publikováno v:
Clays and Clay Minerals. 42:18-22
Saponites were hydrothermally grown in the presence of amounts of NH4+, Na+, K+, Rb+, Ca2+, Ba2+, and Ce4+ equivalent with the CEC of the saponite (155 meq/100 g), with or without F−, at a temperature of 200°C for 72 hr. XRD and CEC data revealed
Publikováno v:
Journal of Non-Crystalline Solids. 160:144-151
The Al concentration and forced hydrolysis influence the polymerization of aqueous Al(III) and thus the 27Al NMR spectra. An increase of the Al concentration results in an increase of the fraction present as monomer, in the formation of an oligomer o
Publikováno v:
Lithos. 30:167-189
The halogen chemistry of apatites, biotites, amphiboles and titanites from metabasites in the Proterozoic Bamble Sector amphibolite-granulite facies transition zone (Norway) has been studied to gather data on the behaviour of halogens during original
Publikováno v:
Journal of Non-Crystalline Solids. 152:207-211
The 27 Al monomer resonance of 0.05M aluminum nitrate solutions gradually broadens from 7.82 to 89.40 Hz upon forced hydrolysis from an OH/Al molar ratio of 0.0 to 2.2. The broadening is due to increasing amounts of [AlOH] 2+ and [Al(OH) 2 ] + up to
Autor:
John W. Geus, J. Ben H. Jansen, A.M.J. van der Eerden, J. Theo Kloprogge, Roelof D. Schuiling
Publikováno v:
Clays and Clay Minerals. 41:423-430
In the chemical system Na2O-Al2O3-SiO2-H2O, the stability field of Na-beidellite is presented as a function of pressure, temperature, and Na- and Si-activity. Na0.7-beidellite was hydrothermally synthesized using a stoichiometric gel composition in t
Publikováno v:
Clays and Clay Minerals. 41:103-110
Ammonium-saponite is hydrothermally grown at temperatures below 300°C from a gel with an overall composition corresponding to (NH4)0.6Mg3Si34Al0.6O10(OH)2. The synthetic saponite and coexisting fluid have been characterized by means of X-ray powder
Publikováno v:
Journal of Non-Crystalline Solids. 146:111-120
Simplified kinetics are used to describe the rates of hydrolysis and condensation in a Si(OCH3)4/CD3OD/H2O/HCl sol-gel system with H2O/Si = 8. The kinetics of the system can be expressed by three principal reactions: hydrolysis, esterification and wa