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Publikováno v:
Analytica Chimica Acta. 542:97-103
Molecularly imprinted polymers (MIPs) possessing a good binding ability for the family of sulfonylurea herbicides were prepared using 4- or 2-vinyl pyridine as functional monomers and ethylene glycol dimethylacrylate as a crosslinker. Metsulfuron met
Publikováno v:
Macromolecules. 37:2643-2649
We investigate, using small-angle neutron scattering (SANS), the polymer concentration fluctuations in a particular type of end-linked polystyrene gels, in the swollen state. These gels are obtained from the cross-linking of well-defined end-capped l
Publikováno v:
ResearcherID
We have studied end-linked polystyrene networks containing labeled (deuterated) free chains subjected to an uniaxial deformation using small-angle neutron scattering (SANS). The networks are made by end-linking protonated polystyrene precursor chains
Autor:
J. Bastide, François Boué
Publikováno v:
ResearcherID
By considering fractal topologies of polymer networks, we show that one can obtain much smaller values of the elastic modulus than predicted by classical models for the same density of crosslinks. In a regular fractal such as the Sierpinski gasket, o
Autor:
Gérard Beinert, J.P. Munch, J.F. Palierne, J. Bastide, A. Pouchelon, François Boué, C. Rouf-George, F. Isel
Publikováno v:
Polymer Gels and Networks. 4:435-450
We studied polydimethylsiloxane networks prepared by end-linking in the bulk. Neutron scattering and scanning light-scattering experiments indicate that the networks swollen with a “good solvent” exhibit rather strong spatial fluctuations of poly
Publikováno v:
Europhysics Letters (EPL). 32:273-278
Polymer concentration fluctuations in poly(acrylic acid) gels subjected to uniaxial elongation are studied using small-angle neutron scattering (SANS). Different elongation ratios and neutralization degrees are considered. For non-ionized samples and
Publikováno v:
Macromolecules. 28:3570-3587
The small-angle neutron scattering (SANS) was measured from networks containing deuterated un-cross-linked small chains (of molecular weights M WD =14 370 and 73 000) under uniaxial extension of ratio λ up to the maximum value before breaking (λ∼
Autor:
J. Bastide, S. Biagianti-Risbourg
Publikováno v:
Aquatic Toxicology. 31:217-229
Chronological effects produced by 0.17 mg 1−1 atrazine in the liver of juvenile grey mullets (Liza sp) were investigated by means of light and electron microscopy. Fish primarily reacted (day 3 to 9) with a substantial increase in the size of lipid
Publikováno v:
Faraday Discuss.. 101:167-184
The anisotropic small-angle neutron scattering from two different materials is considered. One is a polymer network permeated by free, uncross-linked, deuteriated chains. These free chains behave as mobile species. The other is made up of two network