Mechanistic and kinetic investigation on the formation of palladacyclopentadiene complexes. A novel interpretation involving a bimolecular self-reaction of a monoalkyne intermediate

Autor: Luciano Canovese, Cornelis J. Elsevier, Fabiano Visentin, J. M. Ernsting, A Holuigue, Carlo Levi

Publikováno v: Organometallics, 27(16), 4050-4055. American Chemical Society

The stoichiometric reaction between the complex [Pd(eta(2)-dmfu)(BiPy)] (dmfu = dimethylfumarate; BiPy = 2,2'-bipyridine) and the deactivated alkynes dmbd (dimethyl-2-butynedioate) and pna (methyl (4-nitrophenyl)propynoate), providing the respective

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Mechanistic and Kinetic Investigation on the Formation of Palladacyclopentadiene Complexes. A Novel Interpretation Involving a Bimolecular Self-Reaction of a Monoalkyne Intermediate.

Autor: A. Holuigue, J. M. Ernsting, L. Canovese, C. J. Elsevier, F. Visentin, C. Levi

Publikováno v: Organometallics; Aug2008, Vol. 27 Issue 16, p4050-4055, 6p

Elucidating the Electronic Nature of Rh-based Paddlewheel Catalysts from ¹⁰³ Rh NMR Chemical Shifts: Insights from Quantum Mechanical Calculations.

Autor: Gui X; Max-Planck-Institut für Kohlenforschung, 45470, Mülheim an der RuhrMülheim/Ruhr, Germany., Sorbelli D; Dipartmento di Chimica, Biologia e Biotechnologie, Università Degli Studi Di Perugia, 06123, Perugia, Italy., Caló FP; Max-Planck-Institut für Kohlenforschung, 45470, Mülheim an der RuhrMülheim/Ruhr, Germany., Leutzsch M; Max-Planck-Institut für Kohlenforschung, 45470, Mülheim an der RuhrMülheim/Ruhr, Germany., Patzer M; Max-Planck-Institut für Kohlenforschung, 45470, Mülheim an der RuhrMülheim/Ruhr, Germany., Fürstner A; Max-Planck-Institut für Kohlenforschung, 45470, Mülheim an der RuhrMülheim/Ruhr, Germany., Bistoni G; Max-Planck-Institut für Kohlenforschung, 45470, Mülheim an der RuhrMülheim/Ruhr, Germany.; Dipartmento di Chimica, Biologia e Biotechnologie, Università Degli Studi Di Perugia, 06123, Perugia, Italy., Auer AA; Max-Planck-Institut für Kohlenforschung, 45470, Mülheim an der RuhrMülheim/Ruhr, Germany.

Publikováno v: Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2024 Jan 16; Vol. 30 (4), pp. e202301846. Date of Electronic Publication: 2023 Nov 29.

Arene displacement, C–H activation and acetonitrile insertion reactions enabled by coordination of a functionalized iminophosphorane to a Ru^II–p-cymene scaffold.

Autor: Gourkhede, Rani, Kaur, Bhupinder, Kote, Basvaraj S., Balakrishna, Maravanji S.

Publikováno v: Dalton Transactions: An International Journal of Inorganic Chemistry; 7/7/2024, Vol. 53 Issue 25, p10693-10703, 11p

Structure and bonding in rhodium coordination compounds: a ¹⁰³Rh solid-state NMR and relativistic DFT study.

Autor: Holmes, Sean T., Schönzart, Jasmin, Philips, Adam B., Kimball, James J., Termos, Sara, Altenhof, Adam R., Xu, Yijue, O'Keefe, Christopher A., Autschbach, Jochen, Schurko, Robert W.

Publikováno v: Chemical Science; 2/14/2024, Vol. 15 Issue 6, p2181-2196, 16p