Zobrazeno 1 - 10 of 144 pro vyhledávání: '"J C, Huffman"'
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Effect of Lewis acidity on the synthesis of RuHCl(CO)(phosphine)(2): subtle influence of steric and electronic effects among P(i)Pr(3), P(i)Pr(2)(3,5-(CF(3))(2)C(6)H(3)), and P(i)Pr(2)Me
Autor: A V, Marchenko, J C, Huffman, P, Valerga, M J, Tenorio, M C, Puerta, K G, Caulton
Publikováno v: Inorganic chemistry. 40(25)
To evaluate the influence of steric, electronic, and synthetic factors, the synthesis of RuHCl(CO)[P(i)Pr(2)(3,5-(CF(3))(2)C(6)H(3))](2) was carried out, and its Lewis acidity toward Cl- was compared to that of RuHCl(CO)(P(i)Pr(3))(2). In this synthe
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::22634587647f95fb05611442db8b261e
https://pubmed.ncbi.nlm.nih.gov/11720500
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7
A comparison of the influences of alkoxide and thiolate ligands on the electronic structure and reactivity of molybdenum(3+) and tungsten(3+) complexes. preparation and structures of M(2)(O(T)Bu)(2)(S(t)Bu)(4), [Mo(S(t)Bu)(3)(NO)](2), and W(S(t)Bu)(3)(NO)(py)
Autor: M H, Chisholm, E R, Davidson, J C, Huffman, K B, Quinlan
Publikováno v: Journal of the American Chemical Society. 123(39)
M(2)(O(t)Bu)(6) compounds (M = Mo, W) react in hydrocarbon solvents with an excess of (t)BuSH to give M(2)(O(t)Bu)(2)(S(t)Bu)(4), red, air- and temperature-sensitive compounds. (1)H NMR studies reveal the equilibrium M(2)(O(t)Bu)(6) + 4(t)BuSH==M(2)(
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::5cbffe1c241c2263001e7230e2fcfcde
https://pubmed.ncbi.nlm.nih.gov/11572687
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8
Single-molecule magnets: preparation and properties of mixed-carboxylate complexes
Autor: M, Soler, P, Artus, K, Folting, J C, Huffman, D N, Hendrickson, G, Christou
Publikováno v: Inorganic chemistry. 40(19)
Methods are reported for the preparation of mixed-carboxylate versions of the [Mn(12)O(12)(O(2)CR)(16)(H(2)O)(4)] family of single-molecule magnets (SMMs). [Mn(12)O(12)(O(2)CCHCl(2))(8)(O(2)CCH(2)Bu(t))(8)(H(2)O)(3)] (5) and [Mn(12)O(12)(O(2)CHCl(2))
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::2c24121c47516f26c0532989029c3b4a
https://pubmed.ncbi.nlm.nih.gov/11531438
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9
Unsaturated Ru(0) species with a constrained bis-phosphine ligand: [Ru(CO)2(tBu2PCH2CH2PtBu2)]2. Comparison to [Ru(CO)2(PtBu2Me)2]
Autor: T, Gottschalk-Gaudig, J C, Huffman, H, Gérard, O, Eisenstein, K G, Caulton
Publikováno v: Inorganic chemistry. 39(18)
The synthesis of Ru(C2H4)(CO)2(dtbpe) (dtbpe = tBu2PC2H4PtBu2), then green [Ru(CO)2(dtbpe)]n is described. In solution, n = 1, while in the solid state, n = 2; the dimer has two carbonyl bridges. DFTPW91, MP2, and CCSD(T) calculations show that the p
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::49c148cb23a166982f301323f95763e9
https://pubmed.ncbi.nlm.nih.gov/11198847
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