Synthesis of clay-armored poly(vinylidene chloride-co-methyl acrylate) latexes by Pickering emulsion polymerization and their film-forming properties

Autor: Isabelle Chaduc, Muriel Lansalot, Pierre-Emmanuel Dufils, Jérôme Vinas, Laura Delafresnaye, Pierre-Yves Dugas, Elodie Bourgeat-Lami

Publikováno v: Polymer Chemistry
Polymer Chemistry, Royal Society of Chemistry-RSC, 2017, 8 (40), pp.6217-6232. ⟨10.1039/c7py00902j⟩

We report the surfactant-free emulsion copolymerization of styrene (Sty)/methyl acrylate (MA) and vinylidene chloride (VDC)/MA by using clay platelets (LAPONITE® or a mixture of LAPONITE® and Montmorillonite) as Pickering stabilizers. Several param

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::093a8c08fb19611c6145ff50febab8a3
https://doi.org/10.1039/c7py00902j

Selective and Quantitative Oxidation of Xanthate End-Groups of RAFT Poly( n -butyl acrylate) Latexes by Ozonolysis

Autor: Jérôme Vinas, Dimitri Matioszek, Mathias Destarac, Pierre-Emmanuel Dufils

Publikováno v: Macromolecular Rapid Communications
Macromolecular Rapid Communications, Wiley-VCH Verlag, 2015, 36 (14), pp.1354-1361. ⟨10.1002/marc.201500115⟩
Macromolecular Rapid Communications, 2015, 36 (14), pp.1354-1361. ⟨10.1002/marc.201500115⟩

Although various successful strategies have been reported in the past for the postpolymerization modification of the reversible addition-fragmentation chain transfer (RAFT) terminal group in homogeneous media, no solution is proposed for the tedious

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f0bbf56282e9bede87dd451e935e2125
https://hal.archives-ouvertes.fr/hal-02195491

Poly(vinylidene chloride)-Based Amphiphilic Block Copolymers

Autor: Pierre-Emmanuel Dufils, Muriel Lansalot, Bernadette Charleux, François Stoffelbach, Gaëlle Pembouong, Jérôme Vinas, Franck D'Agosto, Jutta Rieger, Emilie Velasquez, Olivier Boyron

Publikováno v: Macromolecules
Macromolecules, 2013, 46 (3), pp.664-673. ⟨10.1021/ma302339x⟩
Macromolecules, American Chemical Society, 2013, 46 (3), pp.664-673. ⟨10.1021/ma302339x⟩
BASE-Bielefeld Academic Search Engine

The controlled/living free-radical copolymerization of vinylidene chloride (VDC) with methyl acrylate (MeA) or acrylic acid (AA) was studied by the reversible addition–fragmentation chain transfer (RAFT) technique using a trithiocarbonate RAFT agen

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e8ac2e9c41744b4ee757d9c5e0073102
https://hal.science/hal-01877406

Sulfonated macro-RAFT agents for the surfactant-free synthesis of cerium oxide-based hybrid latexes

Autor: Jérôme Garnier, Patrick Lacroix-Desmazes, Jérôme Vinas, Jérôme Warnant, Alex M. van Herk, Pierre-Emmanuel Dufils

Publikováno v: Journal of Colloid and Interface Science
Journal of Colloid and Interface Science, Elsevier, 2013, 407, pp.273-281. ⟨10.1016/j.jcis.2013.06.037⟩
Journal of Colloid and Interface Science, 407, 273-281. Academic Press Inc.

Three types of amphiphatic macro-RAFT agents were employed as compatibilizers to promote the polymerization reaction at the surface of nanoceria for the synthesis of CeO2-based hybrid latexes. Macro-RAFT copolymers and terpolymers were first synthesi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f11e1bf8ed49a74c5cef828639381e63
https://hal.archives-ouvertes.fr/hal-00874572

An Emulsifier-Free RAFT-Mediated Process for the Efficient Synthesis of Cerium Oxide/Polymer Hybrid Latexes

Autor: Patrick Lacroix-Desmazes, Jérôme Vinas, Jérôme Warnant, Pierre-Emmanuel Dufils, Yves Vanderveken, Alex M. van Herk, Jérôme Garnier

Publikováno v: Macromolecular Rapid Communications
Macromolecular Rapid Communications, Wiley-VCH Verlag, 2012, 33, pp.1388-1392. ⟨10.1002/marc.201200093⟩
Macromolecular Rapid Communications, 33(16), 1388-1392. Wiley-VCH Verlag

Hybrid latexes based on cerium oxide nanoparticles are synthesized via an emulsifier-free process of emulsion polymerization employing amphiphatic macro-RAFT agents. Poly(butyl acrylate-co-acrylic acid) random oligomers of various compositions and ch

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1ada2438be614e97849048d566701ef4
https://hal.archives-ouvertes.fr/hal-00706707