Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Ivan Veselý"'
Publikováno v:
Collection of Czechoslovak Chemical Communications. 61:1509-1519
New synthesis of intermediates for the preparation of prostaglandin analogs of the E1 series is described. The simple synthesis starts from commercially accessible Corey acetate 1 and makes use of simultaneous protection of the two hydroxy groups in
Autor:
Jaroslav Paleček, Ivan Veselý
Publikováno v:
Collection of Czechoslovak Chemical Communications. 60:1242-1246
This paper describes a new synthesis of monomeric 2-/(2-methyl-2-propenoyl)oxy/ethyl esters of prostaglandins (IIa-IId). The monomeric esters were prepared by reaction of an alkali metal or triethylammonium salt of a prostaglandin of the F2a or A2 se
Publikováno v:
Collection of Czechoslovak Chemical Communications. 57:357-361
The (-)-enantiomer of Corey lactone Ia has been separated from its (+)-enantiomer Ib via enantioselective esterification of the latter using glycerol tributyrate and catalytic amount of lipase from Candida cylindracea (EC 3.1.1.3) in an aprotic solve
Publikováno v:
Collection of Czechoslovak Chemical Communications. 56:1690-1700
Racemic hydrogen butanedioates (IIa, IIb) and hydrogen pentanedioates (IIIa, IIIb), prepared by reaction of racemic Corey alcohols Ia, Ib with the corresponding acid anhydride, were resolved by optically active bases [(1R,2S)-(-)-ephedrine, (S)-(-)-1
Autor:
Ivan Veselý
Publikováno v:
Geografie. 83:225-237
The territory investigated is situated in the middle part af the Czechoslovak Socialist Republic, approximately 20 km westward from the town of Olomouc. The geomorphological unit of the Bouzovská vrchovina (highland) is a component part of the Záb
Publikováno v:
Collection of Czechoslovak Chemical Communications. 52:1583-1588
PGF2α I and its synthetic analogs Cloprostenol II and Fluprostenol III form crystalline complexes with AgNO3. Application of these compounds to the production of pure prostaglandins is described. 1H and 13C NMR spectra are also discussed.
Autor:
Ivan Veselý, Václav Dědek
Publikováno v:
Collection of Czechoslovak Chemical Communications. 50:1948-1958
Cleavage of 3,3,4-trifluoro-2,2-dimethyloxetane (I) in an aqueous solution of sulphuric acid, phosphoric acid, hydrogen chloride, or hydrogen bromide gave a mixture of 2,2-difluoro-3-methyl-3-butenal (II) and 5,5-difluoro-2-(1,1-difluoro-2-hydroxy-2-
Publikováno v:
Collection of Czechoslovak Chemical Communications. 54:1683-1686
Very convenient synthesis of Corey lactone–(3aα,4α,5β,6aα)-5-(1,1'-biphenyl-4-carbonyloxy)-hexahydro-4-hydroxymethyl-2H-cyclopenta[b]furan-2-one (VI) was developed. The title compound was obtained in five steps starting from 7-anti-hydroxymethy
Autor:
Václav Dědek, Ivan Veselý
Publikováno v:
Collection of Czechoslovak Chemical Communications. 50:2730-2742
Addition of nucleophiles to 2,2-difluoro-3-methyl-3-butenal (I) is complicated by its spontaneous polymerization. Compound I afforded neither hydrate nor dimethyl acetal but reacted with ethylene glycol to give the cyclic acetal II. Reaction with ace
Publikováno v:
Earth and Planetary Science Letters. 5:153-158
The results of 7 temperature measurements repeated in bore hole MB-5A have been analyzed, and the character of the disturbance of the natural temperature field during hole boring has been studied. The results make it possible to determine the heat tr