Zobrazeno 1 - 10
of 25
pro vyhledávání: '"Ivan Sekerka"'
Publikováno v:
International Journal of Environmental Analytical Chemistry. 63:153-165
Thallium is a highly toxic, under-studied priority element. However, it has recently created much interest due to afresh and rapid improvements in detection limit. It appears that there are no published T1 data for Great Lakes waters, likely due to t
Publikováno v:
Journal of Great Lakes Research. 21:384-394
While being a highly toxic element, thallium (Tl) has been studied to a much lesser degree than other toxic elements such as lead, cadmium or mercury. This is mainly because Tl is often undetected by classical analytical methods which tend to have po
Publikováno v:
International Journal of Environmental Analytical Chemistry. 53:13-27
This paper reports for the first time the application of a Laser-Excited Atomic Fluorescence Spectrometer (LEAFS) to study lead distribution in the Great Lakes waters. A class 100 clean laboratory for in-house work and a portable clean lab for field
Publikováno v:
Microchemical Journal. 47:345-350
A novel, simple and cost-effective method has been developed for tuning dye lasers used in laser-excited atomic fluorescence spectrometry. The method uses two common laboratory items-a pierced mirror and a commercial electrodeless discharge lamp (EDL
Publikováno v:
Analytica Chimica Acta. 269:129-136
A copper vapor laser-pumped dye laser was used in the development of a laser-excited atomic fluorescence spectrometer, which was optimized to give low-ng 1 −1 sensitivity. Using the spectrometer, a method was developed for direct determination of l
Publikováno v:
Journal of Analytical Atomic Spectrometry. 9:315
This paper describes a laser-excited atomic fluorescence spectrometric method for direct determination of lead in sea-waters down to femtogram levels. No separation/concentration steps nor chemical modifier were used. A programmable, in situ, known a
Autor:
Ivan Sekerka, Joseph F. Lechner
Publikováno v:
Analytical Letters. 9:1099-1110
The analytical behaviour of solid state, ion-selective electrodes based on silver or mercury sulfide, selenide, or telluride matrices was studied. As the active component, the chalcogenides of Cu, Pb, Cd, Zn, Ni, Co, and Bi for the cation electrodes
Autor:
Milan Remko, Ivan Sekerka
Publikováno v:
Zeitschrift für Physikalische Chemie. 134:135-148
Publikováno v:
Collection of Czechoslovak Chemical Communications. 48:3214-3222
The PCILO quantum-chemical method with geometry optimization has been used to study rotation barriers of methyl groups in N-methylacetamide and N,N-dimethylacetamide. In all the cases studied, the eclipsed conformation have been found to be the most
Autor:
Ivan Sekerka, Milan Remko
Publikováno v:
Collection of Czechoslovak Chemical Communications. 52:1879-1887
The PCILO quantum chemical method was applied to the study of 1-[2-(2-methoxyphenylcarbamoyloxy)ethyl]piperidine (B), its cation (BH+), and hydrofluoride (BHF). For B and BH+, their principal hydration sites were established. Conformation maps of the