Zobrazeno 1 - 10
of 28
pro vyhledávání: '"Ivan Schopov"'
Publikováno v:
Polymer Bulletin. 46:345-349
A new methacrylate monomer containing anthracene moiety connected with long flexible spacer was prepared and copolymerized with n-butyl methacrylate. It has been found that upon illumination in inert atmosphere photodimerization of the anthracene rin
Publikováno v:
Macromolecular Chemistry and Physics. 201:1134-1140
Four poly(oxymethyleneanthrylene)s were prepared by polycondensation of 9,10-diacetoxyanthracene (and a substituted analogue) with α,ω-dibromoalkanes. Two model compounds were also synthesized by the same procedure. Although non-conjugated the poly
Publikováno v:
Macromolecular Chemistry and Physics. 198:919-925
Doping with iodine of the liquid crystalline polymer [OPhCH=NPhN=CHPhO(CH 2 ) 3 SiMe 2 OSiMe 2 OSiMe 2 (CH 2 ) 3 ] n in its different states was investigated for the first time. It was established that the polymer cannot be doped in solution, but it
Publikováno v:
Macromolecular Chemistry and Physics. 197:1713-1720
In order to elucidate the dependence of electrical conductivity on conjugation length, polyketones built up of short conjugated aromatic blocks and methylene chains of different length were studied. As obtained, the polymer exhibit very low electrica
Publikováno v:
European Polymer Journal. 29:617-620
A new polymer, poly(1,3,4-oxadiazole-2,5-diyl-ethenyl-1,4-phenylene), was obtained from p -phenylenediacrylic acid and hydrazine sulphate in methanesulphonic acid containing P 2 O 5 . The all- trans configuration of the double bonds and the chemical
Autor:
Ivan Schopov, Lyudmila Mladenova
Publikováno v:
Synthetic Metals. 48:249-258
Two new polymers with methylene bridged rans-cisoid polyene chains are prepared by the carbonyl-olefin exchange reaction. Since the single bonds of the chain are included in the rings, any free rotation along them is prevented and therefore the conju
Publikováno v:
Advanced Materials. 12:1058-1060
Autor:
Christo Jossifov, Ivan Schopov
Publikováno v:
Die Makromolekulare Chemie. 192:857-861
The influence of experimental conditions and the nature of the catalytic system on the yield of products insoluble in methanol from the carbonyl-olefin exchange reaction (COER) was investigated. It was established that the COER of some α, β-unsatur
Autor:
Ivan Schopov, Christo Jossifov
Publikováno v:
Die Makromolekulare Chemie. 192:863-866
The processes which take place with the α,β-unsaturated compound 1,2,3,3-tetraphenyl-2-propen-1-one (1) under the influence of WCl6 were investigated. Special attention was paid to the low-molecular-weight products. It was established that beside p
Publikováno v:
Polymer. 35:1549-1551
A polymer containing photochromic moieties is obtained by means of the transesterification of poly(vinyl acetate) with 2-phenyl-5-carboxy-1,3-indandione. Upon u.v. irradiation of a solution and film of this polymer a transition to its benzalphthalide