Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Ivan D, Sorokin"'
Autor:
Ivan D. Sorokin, Oleg I. Gromov, Vladimir I. Pergushov, Daria A. Pomogailo, Mikhail Ya. Melnikov
Publikováno v:
Mendeleev Communications. 31:343-346
Autor:
Oleg I. Gromov, Mikhail Ya. Melnikov, Ivan D. Sorokin, Vladimir I. Pergushov, Daria A. Pomogailo
Publikováno v:
Mendeleev Communications. 31:343-346
Freon matrices affected the nature of species stabilized upon the X-ray irradiation of frozen 1,7-dioxaspiro[5,5]undecane (DOSU)/CF3CCl3 or DOSU/CFCl3 solutions at 77 K. This manifested in the stabilization of a ring-closed DOSU radical cation (RC) w
Publikováno v:
Moscow University Chemistry Bulletin. 76:1-13
The data on the structure and the features of the photochemical reactions for radical cations (RCs) derived from various oxiranes (epoxides) that can be stabilized in Freon matrices at 77 K are summarized. The nature of the RCs and the products of th
Publikováno v:
Mendeleev Communications. 30:687-696
The classic version of aza-Wittig reactions, namely, reactions between phosphazenes and compounds with polar double bonds, is widely employed in organic synthesis to produce C=N bonds. However, only a limited number of aza-Wittig reactions between ph
Autor:
Daria A. Pomogailo, Vladimir I. Pergushov, Ivan D. Sorokin, Mikhail Ya. Melnikov, Oleg I. Gromov
Publikováno v:
Mendeleev Communications. 31:154-156
The structure and nature of the underlying photochemical transformations of radical cations formed upon irradiation of exo-2,3-norbornene oxide solutions in a CF3CCl3 matrix at 77 K have been established using electron paramagnetic resonance and UV-v
Publikováno v:
Synthesis. 49:3035-3068
Ring opening of donor–acceptor cyclopropanes with various N-nucleophiles provides a simple approach to 1,3-functionalized compounds that are useful building blocks in organic synthesis, especially in assembling various N-heterocycles, including nat
Autor:
Daria A. Pomogailo, Mikhail Ya. Melnikov, Oleg I. Gromov, Ivan D. Sorokin, Vladimir I. Pergushov
Publikováno v:
Mendeleev Communications. 28:618-620
By employing EPR and UV/VIS spectroscopy and quantum chemical techniques, we demonstrated that the radical cations of cyclohexene oxide were stabilized upon radiolysis in freonic matrices at 77 K in their distorted form (with the C–C bond in the ox
Publikováno v:
High Energy Chemistry. 50:362-367
It has been established that the photoinduced process observed in EPR and in optical absorption spectra for 1,4-dithiane radical cations in the CF3CCl3 matrix at 77 K can be ascribed to a “boat”—“twist boat” conformational transition.
Autor:
Mikhail Ya. Melnikov, Oleg I. Gromov, Ivan D. Sorokin, Vladimir I. Pergushov, Irina S. Zharinova
Publikováno v:
Mendeleev Communications. 27:479-481
A reversible photochemical transition between an open pseudoallylic form and a cyclic form has been discovered for methylthiirane radical cations in the matrices of CFCl3 and CF3CCl3 at 77 K.
Publikováno v:
Mendeleev Communications. 26:332-334
The radical cations of aziridine can be stabilized in the matrix of CF3CCl3 at 77 K in a cyclic form.