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Publikováno v:
Journal of Molecular Liquids. :121-131
The transfer enthalpies of - CH 2 - moieties, Δ t H θ ( CH 2 ), have been calculated from the transfer enthalpies of two types of solute, the n-alcohols where there is a single alkyl chain and the tetraalkylammonium ions where four alkyl chains are
Publikováno v:
Journal of Molecular Liquids. 94:145-153
The -CH2- moiety is the basic building block of many hydrophobic molecules and of the hydrophobic parts of amphiphilic molecules. Thus understanding the solvation of -CH2- is central to understanding hydrophobic interactions. In the present paper we
Publikováno v:
J. Chem. Soc., Faraday Trans.. 90:2691-2695
Previous studies have established that the extended coordination model of solvation can satisfactorily account for the variation in the transfer enthalpies of solutes in mixed-solvent systems. However, the model parameter relating to the solute-induc