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Publikováno v:
ChemInform. 45
The cyclotrimerization of alkyne (III) leads to a mixture of two isomers with a modest regioselectivity (86:14), whilst similar reactions of unsymmetrical alkynes (I) and (VIII) proceed with high regioselectivity (from 97:3 to
Publikováno v:
Organic & Biomolecular Chemistry. 11:7653
A nickel-based catalytic system has been developed for [2 + 2 + 2] cyclotrimerization of various alkynes, especially ynoates. This catalytic system enables facile construction of substituted aromatic compounds in excellent yields with high regioselec