Zobrazeno 1 - 10
of 472
pro vyhledávání: '"Isolobal principle"'
Publikováno v:
Angewandte Chemie International Edition. 60:24976-24983
A combined theoretical and experimental approach has been used to study the unusual mechanism of oxidative addition of aryl iodides to [bipyAu(C2 H4 )]+ complexes. The modular nature of this system allowed a systematic assessment of the effects of co
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::96834c2202d82254826dc8b50893596e
https://doi.org/10.1002/anie.202108744
https://doi.org/10.1002/anie.202108744
Publikováno v:
Journal of Energy Chemistry. 61:347-367
Metal cyanamides are an emerging class of functional materials with potential applications in sustainable energy conversion and storage technologies such as catalysis, supercapacitors, photoluminescence and next-gen batteries. The [NCN]2− as the an
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::76566f7f881bd3243e798e954aa179e4
https://doi.org/10.1016/j.jechem.2021.01.006
https://doi.org/10.1016/j.jechem.2021.01.006
Publikováno v:
Inorganic Chemistry. 60:15180-15189
Tetrel Lewis acids are a prospective alternative to commonly employed neutral boranes in frustrated Lewis pair (FLP) chemistry. While cationic tetrylium Lewis acids, being isolobal and iso(valence)electronic, are a natural replacement to boranes, neu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e1220efa285498f2e28468cda425812f
https://doi.org/10.1021/acs.inorgchem.1c01543
https://doi.org/10.1021/acs.inorgchem.1c01543
Autor:
Daniel C. Fredrickson, Kendall R. Kamp
Publikováno v:
Inorganic Chemistry. 60:4779-4791
While simple close-packed arrangements convey a sense of optimization, they can, in fact, host competition between different types of interactions. The TiAl3 structure type, for example, represents...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e4601fba4ab88d68bd2b864431f920d4
https://doi.org/10.1021/acs.inorgchem.0c03740
https://doi.org/10.1021/acs.inorgchem.0c03740
Publikováno v:
Angewandte Chemie (International Ed. in English)
Boron reluctantly forms B=X (X=O, S, Se, Te) moieties, which has stimulated the quest for such species in the past few years. Based on the N,N′‐chelating β‐diketiminato ligand (HNacNac), a new amido imidazoline‐2‐imine ligand system (HAmIm
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::799b9033754aadfc77da456f43a3dda6
https://doi.org/10.1002/anie.202015553
https://doi.org/10.1002/anie.202015553
Autor:
Ming-Der Su, Zheng-Feng Zhang
Publikováno v:
RSC Advances. 11:20070-20080
Three fundamental concepts (aromaticity/basicity/electrophilicity), being heavily used in modern chemistry, have been applied in this work to study the chemical reactivity of six-membered-ring group 13 N-heterocyclic carbenes (G13-6-Rea; G13 = group
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::71812c8b02d039637ba3b69804103e90
https://doi.org/10.1039/d1ra02703d
https://doi.org/10.1039/d1ra02703d
Publikováno v:
Physical Chemistry Chemical Physics. 23:12668-12678
Heteronuclear group 15 metal-iron carbonyl cluster complexes of AmFe(CO)n- (A = Sb, Bi; m, n = 2-3) were generated in the gas phase and studied by infrared photodissociation spectroscopy in the carbonyl stretching region. Their structures were determ
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a7b68e228cc6c476afc8df45ae5fd123
https://doi.org/10.1039/d1cp00583a
https://doi.org/10.1039/d1cp00583a
Publikováno v:
Journal of Cluster Science. 32:929-935
The dianionic cluster [Os10(µ6-C)(CO)24]2− reacts with excess SbX3 or p-tolylSbX2 to form the monoanionic clusters [Os10{µ4-Sb(p-tolyl)nX2-n}(µ6-C)(CO)24]− (n = 0; X = Cl, I; n = 1, X = Cl) via insertion into an Os–Os bond. Further insertion
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::08af34a735d00b1a9b514d2a58caab12
https://doi.org/10.1007/s10876-020-01857-w
https://doi.org/10.1007/s10876-020-01857-w
Publikováno v:
Chemistry – A European Journal. 26:8819-8827
The "CPNR" ligand may be viewed as being isolobal with fulminate, CNO; however, attempts to prepare a complex of such a ligand resulted instead in a range of novel imino and aminophosphinocarbyne complexes. Sequential treatment of [Mo(≡CBr)(CO)2 (T
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0d1e3d31243834fce03313c4229e7532
https://doi.org/10.1002/chem.202000635
https://doi.org/10.1002/chem.202000635
Autor:
Guy Bertrand, Michele Soleilhavoup
Publikováno v:
Chem. 6:1275-1282
Summary The different modes of stabilization for carbenes are briefly discussed in the context of the discovery of their first stable representatives. Largely because a diversity of stable carbenes are available today, their use has spanned across th
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ae3225aceea67a5c21c69a594e66b799
https://doi.org/10.1016/j.chempr.2020.04.015
https://doi.org/10.1016/j.chempr.2020.04.015