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Autor:
Isao Kanesaka
Publikováno v:
Bulletin of the Chemical Society of Japan. 82:946-952
The isotropic and anisotropic Raman spectra and the infrared spectrum of O–H stretching bands of CH3OH in the liquid state are analyzed on the basis of a self-consistent cluster theory based on Gre...
Autor:
Isao Kanesaka, Eiji Mitsuhashi
Publikováno v:
Bulletin of the Chemical Society of Japan. 81:248-253
Infrared spectra of formamide are wholly simulated for the in-plane modes on the basis of a damped oscillator model, where force constants and intensity parameters and damping constants defined in ...
Autor:
Kaori Kobayashi, Isao Kanesaka
Publikováno v:
Journal of Raman Spectroscopy. 38:436-439
The line shapes of the polarized and depolarized Raman bands of the CO stretching of acetone, as well as the infrared band, are analyzed on the basis of the vibrational coupling model. The analytical procedures are described in detail. Satisfactory a
Publikováno v:
Bulletin of the Chemical Society of Japan. 79:406-412
The infrared intensities of the triclinic and monoclinic crystal modifications of quinhydrone (QH) have been measured, along with those of the parent molecules of p-hydroquinone (HQ) and p-benzoqui...
Autor:
Kaori Kobayashi, Isao Kanesaka
Publikováno v:
Journal of Molecular Structure. 753:80-83
Infrared spectra in the region of the CN stretchings of aqueous KOCN-KSCN binary systems as well as KOCN or KSCN pure solutions are observed in the gel phase of the mono-palmitin-water system, where two-dimensional water layers are formed. Similar ob
Autor:
Isao Kanesaka, Kaori Kobayashi
Publikováno v:
Journal of Molecular Structure. :343-348
Infrared spectra in the region of the CN stretching of aqueous KOCN–KSCN binary systems were observed in order to investigate the vibrational coupling between two oscillators. Additivity in infrared intensities was not found by analyzing each band
Autor:
Isao Kanesaka
Publikováno v:
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 60:297-302
A change in an infrared intensity in dielectric media is treated by an electrostatic model. The basic model is originally formalized for a dipolar liquid. The model is satisfactorily applied to the infrared intensity of the C-H stretching of chlorofo
An investigation on a broad infrared band with the maximum at ∼1300 cm−1 in magnesia cement, phase 3
Autor:
Isao Kanesaka, Rie Shimizu
Publikováno v:
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 59:569-573
In magnesia cement, phase 3, a broad and strong infrared band was observed with the maximum at ∼1300 and 1050 cm −1 in the H and D systems, respectively. To clarify the origin of the 1300 cm −1 band the temperature dependency of the infrared sp
Publikováno v:
Journal of Raman Spectroscopy. 33:26-30
Vibrational spectra of Cd(CN)2·G clathrates were observed and changes in the spectral features with temperature analyzed, deducing phase transitions. A two-step transition was found in the clathrates with G = HCCl3 (Tc = 188, 122 K), HCBr3 (249, 134