Zobrazeno 1 - 10
of 73
pro vyhledávání: '"Irene Brüdgam"'
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 6, Iss 1, Pp 1229-1245 (2010)
A series of γ-oxo esters suitably substituted with various styrene subunits was subjected to samarium diiodide-induced 8-endo-trig cyclizations. Efficacy, regioselectivity and stereoselectivity of these reactions via samarium ketyls strongly depend
Externí odkaz:
https://doaj.org/article/7000b6bb489e49adb23fe557ddc1f079
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 6, Iss 1, p 42 (2010)
A series of trifluoromethyl-substituted 3-alkoxypyridinol derivatives has been deprotected to furnish pyridine-3,4-diol derivatives in good yields. The X-ray crystal structure analysis proved that a 1:1 mixture of pyridine-3,4-diols and their pyridin
Externí odkaz:
https://doaj.org/article/fd8c80c049044df59c5957a00690db65
Publikováno v:
Chemical Physics. 427:87-94
The aim of this work was to describe the vibrations connected with the short hydrogen bonds of differing geometries in 2,4-dinitrobenzoic acid and in 2,4-dinitrobenzoic acid complexed in two ratios with pyridine. All three compounds contain short hyd
Publikováno v:
CrystEngComm. 12:795-800
A solution of potassium nonaflate (n-C4F9SO3K = NfOK) in boiling acetonitrile forms, on subsequent cooling, a stable crystalline 1 : 1 supramolecular complex. The structures of NfOK and NfOK·CH3CN were elucidated by single-crystal X-ray structure de
Publikováno v:
Collection of Czechoslovak Chemical Communications. 74:1069-1080
Addition of lithiated methoxyallene to aziridine derivatives provided the expected primary addition products. The less substituted carbon of the aziridine ring was attacked selectively. The primary adducts could be converted to enantiopure piperidine
Publikováno v:
European Journal of Organic Chemistry. 2009:282-291
Lewis acid promoted rearrangements of different 4-alkoxy-substituted 1,2-oxazines syn-1 are reported. Depending on the nature of this alkoxy group different reaction pathways are possible either providing bicyclic 1,2-oxazinones 2 or the novel tricyc
Publikováno v:
European Journal of Organic Chemistry. 2008:3647-3655
A series of 4-pyridyl nonaflates was coupled with several terminal alkynes to efficiently provide new 4-alkynyl-substituted 3-alkoxypyridine derivatives. Apt conditions were developed for their conversion into furo[2,3-c]pyridines. Sonogashira reacti
Publikováno v:
European Journal of Organic Chemistry. 2008:2325-2335
In this report, we describe our experiments dealing withsamarium diiodide promoted cyclizations of quinolyl-substituted ketones 6–12 and also the attempted reductive cyclization of carbazole-containing ketone 13. These precursors were prepared by H
Publikováno v:
Synlett. 2008:991-994
Proline-promoted Mannich reactions of a series of cycloalkanones with formalin and aniline followed by N-acetylation provided precursors 9- 12 for samarium diiodide mediated cyclizations. The ketyl-aryl coupling of these compounds furnished angularly
Autor:
Boris Egart, Irene Brüdgam, Bettina Bressel, Robert Pulz, Hans-Ulrich Reißig, Ahmed Al-Harrasi
Publikováno v:
European Journal of Organic Chemistry. 2008:467-474
Acid-catalyzed transformations of carbohydrate-derived 3,6-dihydro-2H-1,2-oxazines such as 1, 5 and 13 provided a set of enantiopure furano-1,2-oxazines or pyrano-1,2-oxazines. The reaction conditions determined the degree of solvolysis of the compou