Zobrazeno 1 - 10
of 40
pro vyhledávání: '"Inge Sänger"'
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 5, Pp 544-546 (2015)
In the title salt, [Ag(C27H36N2)2]Cl·C4H8O, the AgI atom is coordinated by two 1,3-bis(2,6-dimethylphenyl)imidazol-2-ylidene ligands. The imidazole rings are inclined to one another by 46.69 (13)° and the benzene rings in each ligand are almost nor
Externí odkaz:
https://doaj.org/article/0dc6286ae8074a6ab168b55983dd1336
Publikováno v:
Acta Crystallographica Section E, Vol 68, Iss 5, Pp m708-m708 (2012)
The AuI atom of the title compound, [AuI(C12H27P)], shows an almost linear coordination, with a P—Au—I angle of 178.52 (3)° [Au—P = 2.2723 (14) Å and Au—I = 2.5626 (6) Å].
Externí odkaz:
https://doaj.org/article/8d944bf6c1f140c48e483041bb2e0553
Publikováno v:
Zeitschrift für Naturforschung B. 74:153-158
The donor-free potassium silanide K[SiPh3] was prepared by the reaction of hexaphenyldisilane, Ph3Si–SiPh3, with potassium metal in benzene at room temperature. The solid-state structure, determined by powder X-ray diffraction consists of {K[SiPh3]
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 644:925-929
Publikováno v:
Zeitschrift für Naturforschung B. 71:1219-1224
When 4,4a-dihydro-3,3-dimethyl-1-phenyl-4,4-bis(trimethylsilyl)-3H-2-oxa-3-sila-naphthaline (silaoxine C22H34OSi3 (3); orthorhombic, space group Pna21, Z=4) was thermolized in a CO2 atmosphere, the corresponding oxasilacyclobutane (silaoxetane) 5 was
Autor:
Jan W. Bats, Michael Bolte, Hans-Wolfram Lerner, Inge Sänger, Matthias Wagner, Annika Herrmann
Publikováno v:
ChemistrySelect. 1:1484-1489
The reaction of SiCl4 with Na[SitBu3] in thf at −78 °C yielded tBu3Si-SiCl3 along with tBu3SiCl, tBu3Si-SitBu3, and tBu3SiH. After HPLC separation we isolated crystalline tBu3Si-SiCl3 from the eluate (retention time: τ = 39 min). During the work-
Publikováno v:
Zeitschrift für Naturforschung B. 71:135-139
Treatment of P4with one equivalent of Li[SitBu3] leads to the formation of a number of oligo-phosphanes and -phosphides, e.g. the bicyclo[1.1.0]tetraphosphane P4(SitBu3)2, the heptaphosphanortricyclane P7(SitBu3)3, the tetraphosphides Li3[P(PSitBu3)3
Unexpected Silaazetidine Formation in the Thermolysis of thf-Supported Silanimine Et2Si=N-SitBu3·thf
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 642:96-100
The silyl amide Et2SiCl-NLi-SitBu3 can be cleanly prepared from precursor silylamine Et2SiCl-NH-SitBu3 and Li[nBu]. The CF3SO3SiMe3 induced LiCl elimination of Et2SiCl-NLi-SitBu3 in thf afforded a 2-silaazetidine derivative by [2+2] cycloaddition of
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 5, Pp 544-546 (2015)
Acta Crystallographica Section E: Crystallographic Communications
Acta Crystallographica Section E: Crystallographic Communications
In the title compound, the silver atom is coordinated by two 1,3-bis(2,6-dimethylphenyl)imidazol-2-ylidene ligands, with the imidazole rings inclined to one another by 46.69 (13)°. In the crystal, molecules are linked by trifurcated C—
Autor:
Inge Sänger, Günter Margraf, Hans-Wolfram Lerner, Matthias Wagner, Michael Bolte, Frauke Schödel
Publikováno v:
Zeitschrift für Naturforschung B. 67:549-556
The bis(trimethyl)silylamido complex Na(THF){Fe[N(SiMe3)2]3} and the disilane tBu3SiSitBu3 were obtained from the reaction of Fe[N(SiMe3)2]3 with the sodium silanide Na(THF)2[SitBu3] in a mixture of benzene and THF. Single crystals of Na(THF){Fe[N(Si