Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Ilias Pavlakos"'
Autor:
Abil E. Aliev, William B. Motherwell, Simon J. Coles, Ilias Pavlakos, Tanzeel Arif, Graham J. Tizzard, Josephine R. T. Arendorf, Rafael B. Moreno
Publikováno v:
Angewandte Chemie International Edition. 57:1193-1198
The relative strength of noncovalent interactions between a thioether sulfur atom and various π systems in designed top pan molecular balances was determined by NMR spectroscopy. Compared to its oxygen counterpart, the sulfur atom displays a remarka
Autor:
Graham J. Tizzard, William B. Motherwell, Simon J. Coles, Ilias Pavlakos, Tanzeel Arif, Abil E. Aliev
Publikováno v:
Angewandte Chemie. 127:8287-8292
A comparative study using NMR spectroscopy and designed top-pan molecular balances demonstrates that the noncovalent interaction of a hydroxy group with π-deficient pyrazine and quinoxaline units involves a lone pair-heteroarene interaction which is
Autor:
Abil E. Aliev, Josephine R. T. Arendorf, Ilias Pavlakos, Rafael B. Moreno, Michael J. Porter, Henry S. Rzepa, William B. Motherwell
Publikováno v:
Angewandte Chemie. 127:561-565
Publikováno v:
Chem. Commun.. 48:1958-1960
A new and very rapid access to indoline intermediates useful for the synthesis of alkaloids related to the stephacidins has been established using a radical cascade process initiated from a sulphur-substituted diketopiperazine.
Autor:
William B. Motherwell, Ilias Pavlakos, Henry Rzepa, Michael J. Porter, Rafael B. Moreno, Josephine R. T. Arendorf, Abil E. Aliev
Publikováno v:
Angewandte Chemie (International ed. in English). 54(2)
A comparative study of molecular balances by NMR spectroscopy indicates that noncovalent functional-group interactions with an arene dominate over those with an alkene, and that a p-facial intramolecular hydrogen bond from a hydroxy group to an arene
Publikováno v:
ChemInform. 44
Publikováno v:
Organicbiomolecular chemistry. 11(30)
A strategy for the synthesis of members of the prenylated indole alkaloid family is described, which involves a radical cascade process of an appropriately substituted diketopiperazine (DKP) core structure. Several approaches to the generation of the
Publikováno v:
ChemInform. 43
This radical cascade reaction initiated from sulfur-substituted diketopiperazine (I) affords indolines as key stepping stones to avrainvillamide, stephacidin B, and their bioactive analogues.