Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Ilia J. Kobylianskii"'
Publikováno v:
Organometallics. 34:1301-1306
Herein we disclose experimental and in silico gas-phase studies of β-methyl and β-hydride elimination from cationic diphosphine palladium(II) neopentyl and isobutyl complexes. In particular, we have determined activation barriers for these transfor
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::dfdafe6ff0a4e11e4f0d68c14c64641a
https://doi.org/10.1021/acs.organomet.5b00043
https://doi.org/10.1021/acs.organomet.5b00043
Publikováno v:
Journal of the American Chemical Society, vol 140, iss 1
Zhukhovitskiy, AV; Kobylianskii, IJ; Wu, CY; & Toste, FD. (2018). Migratory Insertion of Carbenes into Au(III)-C Bonds. Journal of the American Chemical Society, 140(1), 466-474. doi: 10.1021/jacs.7b11435. UC Berkeley: Retrieved from: http://www.escholarship.org/uc/item/70z8q1dm
Journal of the American Chemical Society
Zhukhovitskiy, AV; Kobylianskii, IJ; Wu, CY; & Toste, FD. (2018). Migratory Insertion of Carbenes into Au(III)-C Bonds. Journal of the American Chemical Society, 140(1), 466-474. doi: 10.1021/jacs.7b11435. UC Berkeley: Retrieved from: http://www.escholarship.org/uc/item/70z8q1dm
Journal of the American Chemical Society
© 2017 American Chemical Society. Migratory insertion of carbon-based species into transition-metal-carbon bonds is a mechanistic manifold of vast significance: it underlies the Fischer-Tropsch process, Mizoroki-Heck reaction, Ziegler-Natta and anal
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::99f0422b9befeea1d25ac8a17a3cf615
https://escholarship.org/uc/item/70z8q1dm
https://escholarship.org/uc/item/70z8q1dm
Publikováno v:
Journal of the American Chemical Society. AMER CHEMICAL SOC
London dispersion constitutes one of the fundamental interaction forces between atoms and between molecules. While modern computational methods have been developed to describe the strength of dispersive interactions in the gas phase properly, the imp
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b8a33b948491a75213f34f4417f75b09
https://pubmed.ncbi.nlm.nih.gov/28823152
https://pubmed.ncbi.nlm.nih.gov/28823152
Autor:
Megan E. Neubig, F. Dean Toste, Tiffany Chen, Cyril A. Theulier, Ilia J. Kobylianskii, Mustafa Janabi, Mark D. Levin, James P. O'Neil, Cynthia M. Hong
Publikováno v:
Science (New York, N.Y.), vol 356, iss 6344
Trifluoromethylation via broken C-F bonds Trifluoromethyl substituents are widely used in pharmaceutical research to tune the properties of drug candidates. Generally, they are introduced intact through the formation of carbon-carbon bonds. Levin et
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d744e9aed89aa3f99469b8649cf736d0
https://escholarship.org/uc/item/6255j4pr
https://escholarship.org/uc/item/6255j4pr
Publikováno v:
Journal of Fluorine Chemistry. 132:175-180
According to DFT B3LYP/6-31G* calculations the reaction of difluorocarbene with pyridines proceeds reversibly with the formation of thermodynamically unstable intermediates, difluoro-substituted pyridinium ylides, which dissociate to carbene and pyri
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f8b4c3cfc755aa250df767cf0c9d334d
https://doi.org/10.1016/j.jfluchem.2010.12.013
https://doi.org/10.1016/j.jfluchem.2010.12.013
Publikováno v:
Chemistry
The gas-phase bond-dissociation energies of a SO2 -imidazolylidene leaving group of three gold(I) benzyl imidazolium sulfone complexes are reported (E0 =46.6±1.7, 49.6±1.7, and 48.9±2.1 kcal mol(-1) ). Although these energies are similar to each o
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b1164b22f445682f62612a93cc4efed4
https://pubmed.ncbi.nlm.nih.gov/25236486
https://pubmed.ncbi.nlm.nih.gov/25236486
Publikováno v:
J. Am. Chem. Soc.
Essential to biological activity of adenosylcobalamin (AdoCbl) and methylcobalamin (MeCbl) is the Co–C bond cleavage step. Hence, we report an accurate determination of the homolytic gas-phase Co–C bond dissociation energies in the related adenos
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6eecd8702dd80214952f5d1c953b979d
https://pubmed.ncbi.nlm.nih.gov/24007238
https://pubmed.ncbi.nlm.nih.gov/24007238
Publikováno v:
Chemistry - A European Journal. 20:14141-14141
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0b100641867c6cb9c973a0ec96382277
https://doi.org/10.1002/chem.201490182
https://doi.org/10.1002/chem.201490182
Publikováno v:
Organometallics; Apr2015, Vol. 34 Issue 7, p1301-1306, 6p