Stepwise Functionalization of N 2 at Mo: Nitrido to Imido to Amido - Factors Favoring Amine Elimination from the Amido Complex

Autor: Maria F. Espada, Noel Nebra, Eric Clot, Ikram Yagoub, Soukaina Bennaamane, Nathalie Saffon-Merceron, Marie Fustier-Boutignon, Nicolas Mézailles

Publikováno v: European Journal of Inorganic Chemistry
European Journal of Inorganic Chemistry, 2020, 2020 (15-16), pp.1499-1505. ⟨10.1002/ejic.201901295⟩
European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2020, 2020 (15-16), pp.1499-1505. ⟨10.1002/ejic.201901295⟩

International audience; Functionalization of nitrido complex [(P Ph P2 Cy)Mo(N)(I)] by a bis-silane in concentrated medium generates the hydrido-imido complex [(P Ph P2 Cy)Mo(H)(=NSiMe2CH2CH2SiMe2H)(I)]. Abstraction of the iodide by thallium salt TlX

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::000a2929827006d2ee187687b51e0601
https://hal.science/hal-03012876