Výsledky vyhledávání - "Iker Del rosal"

Deactivation of Pd/C catalysts by irreversible loss of hydrogen spillover ability of the carbon support

Autor: Laurent Vanoye, Boris Guicheret, Camila Rivera-Cárcamo, Jérémy Audevard, Javier Navarro-Ruiz, Iker del Rosal, Iann C. Gerber, Cristian H. Campos, Bruno Fernandes Machado, Jérôme Volkman, Régis Philippe, Philippe Serp, Alain Favre-Réguillon

Publikováno v: Journal of Catalysis
Journal of Catalysis, 2023, 424, pp.173-188. ⟨10.1016/j.jcat.2023.05.006⟩

International audience; General interest in solvent-free catalytic processes is driven by the development of environmentally and economically acceptable procedures. Such processes require the use of highly active and stable catalysts. This study repo

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::eea28a8462dbbc53b19b7d905e43747d
https://doi.org/10.1016/j.jcat.2023.05.006

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A versatile strategy for the formation of hydride-bridged actinide–iridium multimetallics

Autor: Christopher Z. Ye, Iker Del Rosal, Michael A. Boreen, Erik T. Ouellette, Dominic R. Russo, Laurent Maron, John Arnold, Clément Camp

Publikováno v: Chemical Science. 14:861-868

Uranium- and thorium-iridium multimetallic species with unprecedented actinide–iridium interactions are prepared via salt-elimination reactions between U/Th halides and K[IrCp*H3].

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f7f2e0f7f5ec53446d1dc582d00aca98
https://doi.org/10.1039/d2sc04903a

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Magnesium(I) Reduction of Aluminum(III) Hydride Complexes: Generation of Mixed Valence Aluminum (AlI/Al0) Hydride Cluster Compounds, [Al6H8(NR3)2{Mg(-diketiminate)}4]

Autor: Sneha Mullassery, K. Yuvaraj, Deepak Dange, Dafydd Jones, Iker del Rosal, Ross Piltz, Alison Edwards, Laurent Maron, Cameron Jones

Reduction of a range of amido- and aryloxy-aluminum dihydride complexes, e.g. [AlH2(NR3){N(SiMe3)2}] (NR3 = NMe3 or N-methylpiperidine (NMP)), with -diketiminato dimagnesium(I) reagents, [{(ArNacnac)Mg}2] (ArNacnac = [HC(MeCNAr)2]-, Ar = mesityl (Mes

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::af0dae267f3cdf78774cdfd312f1e18b
https://doi.org/10.26434/chemrxiv-2023-l84np-v2

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1,2-Palladasilacyclobutene: The Missing Link in the Pd-Catalyzed Annulation of Alkynes for the Silirene-to-Silole Transformation

Autor: Marc Devillard, Chiara Dinoi, Iker Del Rosal, Clément Orione, Marie Cordier, Gilles Alcaraz

Publikováno v: Inorganic Chemistry
Inorganic Chemistry, 2023, 62 (19), pp.7250-7263. ⟨10.1021/acs.inorgchem.3c00045⟩

International audience; The palladium-catalyzed annulation reaction of alkynes enables an attractive approach to siloles. Their access from silirenes and terminal alkynes proved rather general, involving reactive intermediates that have remained elus

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9b5b1629a265a803aa37d18e70d48ce4
https://hal.science/hal-04115375

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Adjustment of the Single Atom/Nanoparticle Ratio in Pd/CNT Catalysts for Phenylacetylene Selective Hydrogenation

Autor: Jérémy Audevard, Javier Navarro‐Ruiz, Vincent Bernardin, Yann Tison, Anna Corrias, Iker Del Rosal, Alain Favre‐Réguillon, Régis Philippe, Iann C. Gerber, Philippe Serp

Publikováno v: ChemCatChem
ChemCatChem, 2023, 15 (11), pp.e202300036. ⟨10.1002/cctc.202300036⟩

International audience; Pd/C catalysts are widely used for hydrogenation reactions in the chemical industry. One of the reasons for their high activity is the ability of Pd nanoparticles (PdNP) to dissociate H2 and promote H-spillover. Nevertheless,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4eec53cc8245aabfb3ca423cef0565c0
https://hal.science/hal-04102599

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Organotitanium Complexes Supported by a Dianionic Pentadentate Ligand

Autor: Warren Piers, Daniel Beh, Alejandro Cuellar De Lucio, Iker del Rosal, Laurent Maron, Denis Spasyuk, Benjamin Gelfand, Jian-Bin Li

The tetrapyralzolylpyridyl diborate pentadentate ligand B2Pz4Py has been complexed to Ti(III) to form the chloro complex (B2Pz4Py)Ti(III)Cl, which is a convenient starting material for preparing alkyl and hydride derivatives of this ligand. The forme

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9fe961e7edee820f57cfa43afea561f2
https://doi.org/10.26434/chemrxiv-2022-c6s6g

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