Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Iaw Ivo Filot"'
Publikováno v:
ACS Catalysis
ACS Catalysis, 7(12), 8050-8060. American Chemical Society
ACS Catalysis, 7(12), 8050-8060. American Chemical Society
The mechanism of CO hydrogenation to CH4 at 260 °C on a cobalt catalyst is investigated using steady-state isotopic transient kinetic analysis (SSITKA) and backward and forward chemical transient kinetic analysis (CTKA). The dependence of CHx reside
Publikováno v:
Chemcatchem
ChemCatChem, 10(1), 136-140. Wiley-VCH Verlag
ChemCatChem, 10(1), 136-140. Wiley-VCH Verlag
The way in which the triple bond in CO dissociates, a key reaction step in the Fischer–Tropsch (FT) reaction, is a subject of intense debate. Direct CO dissociation on a Co catalyst was probed by 12C16O/13C18O scrambling in the absence and presence
Publikováno v:
ACS Catalysis
ACS Catalysis, 7(12), 8061-8071. American Chemical Society
ACS Catalysis, 7(12), 8061-8071. American Chemical Society
Fischer-Tropsch (FT) synthesis is one of the most complex catalyzed chemical reactions in which the chain-growth mechanism that leads to formation of long-chain hydrocarbons is not well understood yet. The present work provides deeper insight into th
Publikováno v:
Chemistry of Materials, 28(16), 5652-5658. American Chemical Society
First-principles calculations have been performed to explore the charge transport process over defective CeO2(111). Charge transport can proceed either by direct migration of the oxygen anion (i.e., vacancy diffusion) or by a polaron-hopping-assisted
Publikováno v:
ACS Catalysis, 8(1), 75-80. American Chemical Society
ACS Catalysis
ACS Catalysis
Doping CeO 2 with Pd atoms has been associated with catalytic CO oxidation, but current surface models do not allow CO adsorption. Here, we report a new structure of Pd-doped CeO 2(111), in which Pd adopts a square planar configuration instead of the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a4498be09d6700c26c045ef64754d301
https://research.tue.nl/nl/publications/a10e421d-ca27-4c59-8ae6-81b90d7a116f
https://research.tue.nl/nl/publications/a10e421d-ca27-4c59-8ae6-81b90d7a116f
Publikováno v:
Chemistry of Materials, 29(21). American Chemical Society
Chemistry of Materials
Chemistry of Materials
We carried out density functional theory calculations to investigate the ripening of Pd clusters on CeO2(111). Starting from stable Pdn clusters (n=1-21), we compared how these clusters can grow through Ostwald ripening and coalescence. As Pd atoms h
Autor:
Iaw Ivo Filot, van Ra Rutger Santen, van Gjha Gert-Jan Heugten, van Jpm Jeaphianne Rijn, Ejm Emiel Hensen, Rjp Robin Broos
Publikováno v:
ACS Catalysis, 5(9), 5453-5467. American Chemical Society
The kinetics of synthesis gas conversion on the stepped Rh(211) surface were investigated by computational methods. DFT calculations were performed to determine the reaction energetics for all elementary reaction steps relevant to the conversion of C
Publikováno v:
Angewandte Chemie, 126(47), 12960-12964. Wiley-VCH Verlag
Angewandte Chemie-International Edition, 53(47), 12746-12750. Wiley
Angewandte Chemie-International Edition, 53(47), 12746-12750. Wiley
Microkinetics simulations are presented based on DFT-determined elementary reaction steps of the Fischer-Tropsch (FT) reaction. The formation of long-chain hydrocarbons occurs on stepped Ru surfaces with CH as the inserting monomer, whereas planar Ru
Autor:
Jjm Jarno Weemers, Christian Müller, Patrick S. Bäuerlein, Fanni Daruny Sypaseuth, Iaw Ivo Filot, Wnp William van der Graaff, Martin Lutz
Publikováno v:
European Journal of Organic Chemistry. 2014:350-362
The development of a novel benzimidazole-derived bidentate P,N-ligand and its application in Ir-catalyzed hydrogenation is described. The ligand backbone was obtained through a one-pot tandem hydroformylation-cyclization sequence and the enantiomers
Publikováno v:
Polymer Chemistry, 4(18), 4955-4965. Royal Society of Chemistry
New thermoset systems based on disulfide bonds were synthesized with self-healing capabilities. The self-healing mechanism is not related to disulfide–disulfide exchange reactions, but to thiol–disulfide exchange reactions that are pH-dependent.