Zobrazeno 1 - 10
of 85
pro vyhledávání: '"Ian Soutar"'
Publikováno v:
Soft Matter. 7:1176-1184
Time-resolved anisotropy measurements (TRAMS) have provided invaluable information concerning the molecular interactions responsible for cononsolvency in the poly(N-isopropylacrylamide), PNIPAM, H2O, and methanol ternary system. TRAMS have successful
Publikováno v:
Macromolecules. 42:9153-9160
This paper reports on the first observation of phosphorescence emission in a thermoresponsive polymer in aqueous media. Random copolymerization of N-isopropylacrylamide, NIPAM, with bromostyrene, BrSTY, promotes efficient intersystem crossing into th
Publikováno v:
Polymer International. 58:273-278
In this review we present data highlighting the power and versatility of luminescence spectroscopy in the study of the conformational behaviour of poly(N-isopropyl acrylamide) (PNIPAM). PNIPAM shows a lower critical solution temperature (LCST) in aqu
Autor:
Giuseppe Battaglia, Lorena Ruiz-Pérez, Linda Swanson, Michael Sommer, Mark Geoghegan, Ian Soutar, Andrew Pryke
Publikováno v:
Macromolecules. 41:2203-2211
Poly(methacrylic acid) (PMAA) undergoes a conformational transition between pH 4 and 6 from a hypercoiled structure to a water-swollen state. There has been much speculation as to the exact nature and driving force of the transition. In this paper, w
Publikováno v:
Journal of Colloid and Interface Science. 303:205-213
Five poly(n-butyl methacrylate), PBMA, latex dispersions have been prepared, each incorporating a different fluorescent label, via a two-stage seeded emulsion polymerization. The resultant latices contain ca. 35% by weight total solids and are of 80
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 180:1-8
In this article we present recent data highlighting the power of (fluorescence) time-resolved anisotropy measurements (TRAMs) in the study of the thermoresponsive behaviour of poly( N -isopropylcrylamide), PNIPAM, and NIPAM-based systems. PNIPAM show
Autor:
Ian Soutar, Linda Swanson
Publikováno v:
Polymer International. 55:729-739
Time-resolved anisotropy measurements (TRAMS) have been used to study the relaxation behaviour of poly(butyl methacrylate) (PBMA) in dilute solution both in toluene and dichloromethane. Various fluorescent labels (residues from copolymerisation of BM
Publikováno v:
Reactive and Functional Polymers. 66:1-11
Fluorescence techniques, particularly time-resolved anisotropy measurements, TRAMS, have confirmed that poly( N -vinylcaprolactam), PNVCap, undergoes a conformational transition from an expanded coil to a compact globule at its lower critical solutio
Publikováno v:
Polymer International. 55:740-748
The synthesis and characterization of poly(N-isopropyl acrylamide) (PNIPAM), which has been grafted to polystyrene, are described. Despite the fact that these copolymers contain around 20 % of the hydrophobic monomer styrene, they still retain water
Publikováno v:
Polymer International. 55:719-728
Fluorescence-quenching measurements have been made on five differently labelled poly(n-butyl methacrylate) latices. The accessibility of the fluorescent label to a freely diffusing quencher (nitromethane, in the case of the current study) gives infor