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ChemInform Abstract: THE CHEMISTRY OF HETEROARYLPHOSPHORUS COMPOUNDS PART 5, THE ALKALINE HYDROLYSIS OF 2-FURYLDIPHENYL-(2-THIENYL)PHOSPHONIUM BROMIDE, AND SOME MIXED HETEROARYLMETHYLPHOSPHONIUM SALTS, RELATIVE STABILITIES OF THE FORMING CARBANIONS

Autor: DAVID W. ALLEN, STEPHEN J. GRAYSON, IAN HARNESS, BARRIE G. HUTLEY, IAN W. MOWAT

Publikováno v: Chemischer Informationsdienst. 5

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::68516fb71aee8ce7e85495f519d04fda
https://doi.org/10.1002/chin.197407323

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The chemistry of heteroarylphosphorus compounds. Part V. The alkaline hydrolysis of 2-furyldiphenyl-(2-thienyl)phosphonium bromide, and some mixed heteroarylmethylphosphonium salts. Relative stabilities of the forming carbanions

Autor: Ian Harness, Ian W. Mowat, Barrie G. Hutley, Stephen J. Grayson, David W. Allen

Publikováno v: Journal of the Chemical Society, Perkin Transactions 2. :1912

Alkaline hydrolysis of 2-furyl(diphenyl)-2-thienyl-phosphonium bromide (V) gives both furan and thiophen in a 1 : 3 molar ratio, indicating that the forming 2-thienyl carbanion is more stable than the 2-furyl analogue, and implying stabilisation of t

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3d4bf59dac6141e961827f3f17ccd8f3
https://doi.org/10.1039/p29730001912

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