Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Ian G. Virrels"'
Autor:
Callie A Weiss, J. Timothy Bays, John C. Linehan, Bruce Scallorn, Thomas E. Bitterwolf, Clement R. Yonker, Michael W. George, Ian G. Virrels
Publikováno v:
European Journal of Inorganic Chemistry. 2001:2619-2624
Photolysis of fresh samples of the η3-allyl compounds [(η5-C5H5)Mo(CO)2(η3-C3H5)] or [(η5-C5H5)Mo(CO)2(η3-C3H4CH3)] in a Nujol matrix at ca. 90 K at a wavelength greater than 400 nm was found by IR spectroscopy to cause conversion of the endo ro
Publikováno v:
Laser Chemistry. 19:245-251
For coordination compounds containing CO or CN groups, fast time-resolved infrared spectroscopy (TRIR) provides a convenient method of probing excited states and intermediates. TRIR has proved particularly powerful for probing the structure and kinet
Publikováno v:
Organometallics. 16:5879-5883
Employing time-resolved IR spectroscopy, we have demonstrated that, following photolysis of [Cp*Cr(CO)2]2 (1) in n-heptane, the only initial photoproduct is the triply bridged CO-loss intermediate ...
Publikováno v:
Organometallics. 16:268-274
The photochemistry of Ru(CO)3(dmpe) (II; dmpe = Me2PCH2CH2PMe2), has been studied by matrix isolation at 12 K and laser flash photolysis with UV−visible and IR detection at ambient temperature. UV photolysis in a matrix results in the formation of
Autor:
David I. Pattison, Mirco Colombo, Ian G. Virrels, T. Q. Ye, Michael W. George, John N. Moore, Robin N. Perutz
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :2857-2860
Laser flash photolysis of [Ru(PPh 3 ) 3 (CO)(H) 2 ] 1 in benzene solution yielded transient [Ru(PPh 3 ) 3 (CO)] which was observed by both microsecond UV/VIS and IR spectroscopy [λ max = 380 nm, ν(CO) = 1845 cm - ] and reacted with H 2 to reform 1
Publikováno v:
Organometallics. 15:4089-4092
Employing time-resolved IR spectroscopy, we have demonstrated that, following photolysis of Cr(CO)4(bpy) (1) in CH2Cl2, the only detectable photoproduct on the 50 ns time scale is the solvated CO-l...
Publikováno v:
Organometallics. 14:5203-5208
Autor:
D. I. Pattison, Michael W. George, John N. Moore, M. G. Colombo, Ian G. Virrels, Robin N. Perutz, T. Q. Ye
Publikováno v:
Laser Chemistry. 19:283-285
Microsecond and picosecond time-resolved infrared studies of Ru(PPh3)3(CO)(H)2 have demonstrated that reductive elimination of H2 is complete within 5 ps of UV photolysis.
Publikováno v:
Chemistry Letters. 25:1089-1090
Time-resolved infrared studies of intermediates generated by photolysis of the title azide in solution at room temperature demonstrated that 3-(methoxycarbonyl)azacycloheptatetraene was the sole intermediate at least in the μs time scale, which is i