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pro vyhledávání: '"Iain Pemberton"'
Publikováno v:
European Journal of Organic Chemistry. 2014:8026-8028
A synthesis for the recently identified, widespread bacterial natural product classes of dialkylresorcinols and cyclohexanediones was developed. The synthesis route is similar to the biosynthesis route in that the formation of the cyclohexanedione ri
Publikováno v:
ChemInform. 46
The crucial step in the synthesis of cyclohexanediones (VI) is the formation of six-membered ring from α,β-unsaturated ketones (IV) and diethyl malonate, followed by saponification and decarboxylation.