Operando Neutron Scattering: Following Reactions in Real Time Using Neutrons

Autor: Iain Hitchcock, Emma K. Gibson, Andrew P. E. York, David J. Nelson, Joe Kelleher, Vainius Skukauskas, Elliot L. B. Johnson Humphrey, Ian P. Silverwood

Publikováno v: Topics in Catalysis. 64:693-698

The complexation of NiCl2 with 2,2'-Bipyridine was followed using quasielastic neutron scattering to observe reaction progress. Water adsorption in chabazite with time resolution was observed using strain induced in the aluminosilicate framework with

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6b8715f624ac64f4687b2472595747e0
https://doi.org/10.1007/s11244-021-01436-x

Hyperpolarised xenon MRI and time-resolved X-ray computed tomography studies of structure-transport relationships in hierarchical porous media

Autor: Christian M. Schlepütz, Iain Hitchcock, Katharine A. Hardstone, Thomas Hotchkiss, Sean P. Rigby, Thomas Meersmann, Fraser Hill-Casey, Galina E. Pavlovskaya, Vladimir Novak

Publikováno v: Chemical Engineering Journal. 405:126750

Catalysed diesel particulate filter (DPF) monoliths are hierarchical porous solids, as demonstrated by mercury porosimetry. Establishing structure-transport relationships, including assessing the general accessibility of the catalyst, is challenging,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3223275803ea823d833c0711d8be439c
https://doi.org/10.1016/j.cej.2020.126750

Effect of Al content on number and location of hydroxyl acid species in zeolites: a DRIFTS quantitative protocol without the need for molar extinction coefficients

Autor: Pierre Bräuer, Iain Hitchcock, Pey Ling Ng, Carmine D'Agostino, Olivia Situmorang

Publikováno v: Brauer, P, Ng, P L, Situmorang, O, Hitchcock, I & D'Agostino, C 2017, ' Effect of Al content on number and location of hydroxyl acid species in zeolites: a DRIFTS quantitative protocol without the need for molar extinction coefficients ', RSC Advances, vol. 7, no. 83, pp. 52604-52613 . https://doi.org/10.1039/c7ra10699h

In this work, we have systematically investigated the effect of the Al content on the number and location of bridging hydroxyls (Bronsted acid sites) and terminal hydroxyls (terminal silanol sites) in ZSM-5 zeolites with varying silica-alumina ratio

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6de0bc50cb7e3e702247b134c76b767e
https://doi.org/10.1039/c7ra10699h

Ammonia mobility in chabazite: insight into the diffusion component of the NH 3-SCR process

Autor: Iain Hitchcock, Sheena Hindocha, Ian P. Silverwood, Andrew P. E. York, C. Richard A. Catlow, Paul Collier, Alexander J. O'Malley, Misbah Sarwar

Publikováno v: O'Malley, A J, Hitchcock, I, Sarwar, M, Silverwood, I P, Hindocha, S, Catlow, C R A, York, A P E & Collier, P J 2016, ' Ammonia mobility in chabazite: insight into the diffusion component of the NH 3-SCR process ', Physical Chemistry Chemical Physics, vol. 18, no. 26, pp. 17159-17168 . https://doi.org/10.1039/C6CP01160H

The diffusion of ammonia in commercial NH3-SCR catalyst Cu-CHA was measured and compared with H-CHA using quasielastic neutron scattering (QENS) and molecular dynamics (MD) simulations to assess the effect of counterion presence on NH3 mobility in au

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3d91c62ea3f4ee5aeb875404562e1346
https://purehost.bath.ac.uk/ws/files/187674108/OMalley_CP_ART_02_2016_001160.R1_revised.pdf

Improving sensitivity and accuracy of pore structural characterisation using scanning curves in integrated gas sorption and mercury porosimetry experiments

Autor: Serafim Bakalis, Marie Lunel, Elizabeth M. Holt, Robin S. Fletcher, Sean P. Rigby, Iain Hitchcock

Publikováno v: Journal of colloid and interface science. 417

Gas sorption scanning curves are increasingly used as a means to supplement the pore structural information implicit in boundary adsorption and desorption isotherms to obtain more detailed pore space descriptors for disordered solids. However, co-ope

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::107550d4937b7415fab8041b9e269a71
https://pubmed.ncbi.nlm.nih.gov/24407663