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pro vyhledávání: '"Iain G. Green"'
Autor:
David M. Smith, Ian W. Harvey, Iain G. Green, Linda J. Dunbar, Robert K. C. Wong, Tom Shepherd, Arshad Ahmad
Publikováno v:
ChemInform. 26
10-Chloroquinoxalino[2,3-c]cinnoline readily undergoes methoxydechlorination when treated with sodium methoxide. The 1-, 2-, 3-, 4- and 9-chloro isomers are unreactive towards this reagent, but the 9,10-dichloro derivative undergoes substitution of b
Publikováno v:
ChemInform. 21
Autor:
Robert K. C. Wong, Linda J. Dunbar, Ian W. Harvey, David M. Smith, Tom Shepherd, Iain G. Green, Arshad Ahmad
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 1. :2751
10-Chloroquinoxalino[2,3-c]cinnoline readily undergoes methoxydechlorination when treated with sodium methoxide. The 1-, 2-, 3-, 4- and 9-chloro isomers are unreactive towards this reagent, but the 9,10-dichloro derivative undergoes substitution of b
Autor:
Brian P. Roberts, Iain G. Green
Publikováno v:
J. Chem. Soc., Perkin Trans. 2. :1597-1606
Liquid-phase e.s.r. studies show that photochemically generated t-butoxyl radicals abstract hydrogen from secondary amine–boranes R2NH→BH3 to give the corresponding amine–boryl radical R2NH→ḂH2 as the kinetically controlled product. Dependi
Publikováno v:
J. Chem. Soc., Perkin Trans. 2. :1773-1779
Photochemically generated alkoxyl or cyclopropyl, but not n-propyl, radicals abstract hydrogen from t-butyl isocyanide–borane (TBIB) to give the corresponding isocyanide–boryl radical ButNC→BH2(1), which has been studied in solution using e.s.r
Publikováno v:
ChemInform. 19
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :1963
The reactions of silyl radicals R3Si˙(R = Me, CD3, Et, MeO, ButO, or Me3SiO) with aminoboranes R1R2N[graphic omitted]BH2 in solution have been studied using e.s.r. spectroscopy. The silyl radicals add rapidly at low temperatures to 2,2,6,6-tetrameth